Thermoplastic Elastomer Powders for Low Density 3D Moldings

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Solution Overview

Problem

Current 3D printing technologies using thermoplastic powders face challenges in producing objects with multiple materials or properties, particularly in achieving low density and high rebound resilience, which is essential for expanding prototyping into end-use parts, especially in automotive and footwear industries.

Innovation Solution

Development of thermoplastic elastomer (TPE) powders with specific particle size and sphericity ranges, combined with a process of pulverizing foamed TPE materials and adding auxiliary agents, allows for the creation of 3D moldings with varying properties such as density and rebound resilience through selective bonding techniques like laser sintering.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of moving object

If conventional thermoplastic powders are used for 3D printing, then the printing process can be performed, but the resulting parts have high density and low rebound resilience

Engineering Contradiction:
ImprovedensityVSAvoidrebound resilience
Core Design Contradiction:
Weight of moving objectVSReliability

Solution Approach 1:

The patent uses TPE (thermoplastic elastomer) powders as a composite material that combines the benefits of low density with high rebound resilience. The TPE material itself is a composite structure that allows achieving both lightweight properties and mechanical performance, resolving the contradiction between density and rebound resilience in 3D printed parts.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the material parameters by selecting TPE powders with specific properties (particle size D50: 10-1000 μm, sphericity A: 0.05-0.65, sphericity B: 0.05-0.65). By optimizing these parameters, the patent achieves both low density and high rebound resilience, transforming the material characteristics to simultaneously improve both contradictory features.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If conventional thermoplastic powders are used, then printing can be performed, but it is difficult to produce parts with multiple materials or multi-performance

Engineering Contradiction:
Improvemulti-material capabilityVSAvoidprinting process complexity
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The patent makes the TPE powder material universal by optimizing its properties (particle size, sphericity) to work effectively with various 3D printing technologies (SLS, MJF, SHS). This single material can be used across different printing processes and can produce parts with varying properties by adjusting printing parameters, achieving multi-functionality without requiring multiple specialized materials for each application.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent enables local quality variations within the printed part by using TPE powders that can be selectively processed. Different regions of the printed part can have different densities and properties by controlling the printing parameters (laser power, scan speed, layer thickness) during the manufacturing process, allowing multi-performance parts from a single material type.

Inventive Principle:
Principle #3Local quality

3Weight of moving object

If density reduction is attempted through process adjustment, then lower density parts may be achieved, but rebound resilience and mechanical properties deteriorate

Engineering Contradiction:
ImprovedensityVSAvoidmechanical properties
Core Design Contradiction:
Weight of moving objectVSStrength

Solution Approach 1:

The patent employs TPE as a composite material that inherently provides both low density and high mechanical properties including rebound resilience. The elastomeric nature of TPE creates a composite structure at the material level that maintains strength and elasticity even at reduced densities, preventing the trade-off between weight reduction and mechanical performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the fundamental material parameter from conventional thermoplastics to TPE with specific characteristics (sphericity 0.05-0.65, particle size 10-1000 μm). This parameter change enables the material to achieve optimal packing and bonding behavior during printing, resulting in parts with both low density and high mechanical properties including rebound resilience above 50%.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach enables the production of 3D moldings with low density and high rebound resilience, along with good mechanical properties, and the ability to create multiple areas with distinct properties using the same material, enhancing the versatility of 3D printed parts.

Implementation Method 1

selective laser sintering

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

selective laser sintering (SLS)

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 3

pulverizing the foamed TPE material

Methodology Applied
Scientific EffectFoaming: Foam

Data Source

PatentUS20240400856A1Thermoplastic elastomer powders, preparing process thereof and method of preparing 3D article
Publication Date: 2024.12.05 BASF SE
  • US20240400856A1 patent drawing
  • US20240400856A1 patent drawing
  • US20240400856A1 patent drawing

AI summary

This disclosure relates to thermoplastic elastomer (TPE) powders, wherein the average particle size D50 of the TPE powders is in the range from 10 μm to 1 mm and at least one of average sphericity A and average sphericity B of TPE powders is no more than 0.6; to a process of preparing the TPE powders and to a method of preparing the 3D molding. The powders and the method according to the present invention allow to prepare a 3D molding with low density, high rebound resilience and good mechanical properties, especially a 3D molding comprising multiple areas having different properties.