Thermoplastic Polyurethane Flame Retardant Composition

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Solution Overview

Problem

Halogen-free flame-retardant thermoplastic polyurethanes face challenges with low aging resistance and deteriorated mechanical properties due to high filling levels of metal hydroxides and other solids, which affects their suitability for various applications.

Innovation Solution

A composition comprising a thermoplastic polyurethane based on diisocyanate and polyester diol with a weight-average molecular weight between 50,000 g/mol and 200,000 g/mol, combined with metal hydroxides and phosphorus-containing flame retardants, and optionally layered silicates or hydrotalcite, which improves aging resistance and mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high filling levels of metal hydroxides and other solids are added to achieve flame retardancy, then flame protection is improved, but mechanical properties deteriorate

Engineering Contradiction:
Improveflame protectionVSAvoidmechanical properties
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent employs a composite flame retardant system combining metal hydroxides (Al(OH)3, Mg(OH)2), phosphorus-containing compounds (phosphates, phosphonates), and nitrogen-containing compounds (melamine, cyanuric acid). This multi-component composite approach creates synergistic effects where each component contributes to flame retardancy through different mechanisms (endothermic decomposition, radical scavenging, char formation), achieving adequate flame protection while reducing the overall filling level required compared to single-component systems, thereby preserving mechanical properties

Inventive Principle:
Principle #40Composite materials

2Reliability

If high filling levels of metal hydroxides and other solids are added to achieve flame retardancy, then flame protection is improved, but processing becomes difficult

Engineering Contradiction:
Improveflame protectionVSAvoidprocessing
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent optimizes the particle size parameters of the metal hydroxides and other solid fillers to improve processability. By controlling particle size distribution and using appropriately sized particles, the composition achieves adequate flow properties and processability during manufacturing while maintaining the necessary flame retardant filling levels. The synergistic flame retardant system also allows for reduced total filler content, further improving processing characteristics

Inventive Principle:
Principle #35Parameter changes

3Reliability

If nitrogen-containing flame retardants are used to achieve flame retardancy, then flame protection is improved, but toxic combustion gases are released

Engineering Contradiction:
Improveflame protectionVSAvoidtoxic combustion gases
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent uses phosphorus-containing compounds as intermediary substances that work synergistically with nitrogen-containing flame retardants. The phosphorus compounds promote char formation and stabilize the flame retardant mechanism, reducing the reliance on nitrogen-containing compounds and thereby minimizing the release of toxic gases like HCN and nitrogen oxides while maintaining adequate flame protection. The phosphorus-nitrogen synergy allows for reduced nitrogen content in the formulation

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition exhibits enhanced aging resistance, good flame retardancy, and maintained mechanical properties, making it suitable for diverse applications without compromising processing difficulties.

Implementation Method 1

metal hydroxides can also be used alone or in combination with phosphorus-containing flame retardants

Methodology Applied
Scientific EffectEndothermic decomposition: Endothermic Reaction

Implementation Method 2

phosphorus-containing flame retardants can be used for halogen-free flame protection of thermoplastic polyurethanes

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Data Source

PatentEP2877537B1Flame retardant thermoplastic polyurethane containing metal hydroxides and polyesterols
Publication Date: 2017.01.18 BASF SE
  • EP2877537B1 patent drawing
  • EP2877537B1 patent drawing
  • EP2877537B1 patent drawing

AI summary

The present invention relates to compositions containing at least one thermoplastic polyurethane, at least one metal hydroxide and at least one phosphorus-containing flame retardant agent, wherein the thermoplastic polyurethane is a thermoplastic polyurethane based on at least one diisocyanate and at least one polyester diol and has a weight-average molecular weight in the range from 50,000 g/mol to 200,000 g/mol, measured by GPC. The present invention further relates to the use of such compositions for producing cable sheaths.