Transition Metal Battery Electrodes to Avoid Dendrites and Flammability

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Solution Overview

Problem

Current commercial batteries using alkali metals face challenges with flammability, dendrite formation, and processing complexity, making it difficult to balance capacity and stability.

Innovation Solution

A rechargeable transition metal battery design featuring a negative electrode made of transition metals or their alloys, a positive electrode with a carbon-based host material and a metal, chalcogen, or halogen compound, and a stable non-flammable electrolyte, which facilitates safe and efficient ion transfer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If alkali metals are used as working ions in commercial batteries, then high electric capacity can be achieved, but flammability and dendrite formation occur

Engineering Contradiction:
Improveelectric capacityVSAvoidbattery stability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent changes the working ion from alkali metal to transition metal, fundamentally altering the electrochemical parameters of the battery system. This substitution maintains high electric capacity while eliminating the flammability and dendrite issues associated with alkali metals, as transition metals have different electrochemical properties including lower reactivity and different ion transport characteristics

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite electrode structures where transition metal materials are combined with conductive matrices and functional coatings. The negative electrode uses transition metal or alloy materials, while the positive electrode combines host materials with transition metal compounds, creating composite structures that optimize both capacity and stability simultaneously

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If alkali metals are used as working ions, then high electric capacity is achieved, but processing complexity and safety issues arise

Engineering Contradiction:
Improveelectric capacityVSAvoidprocessing convenience
Core Design Contradiction:
Use of energy by moving objectVSEase of manufacture

Solution Approach 1:

By changing from alkali metal to transition metal working ions, the patent fundamentally alters the material processing requirements. Transition metals offer better processability with less stringent handling requirements, reduced safety precautions needed during manufacturing, and improved overall ease of manufacture while maintaining high electric capacity

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional battery materials are used, then manufacturing is simpler, but tolerance to moisture and oxygen is lower

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidtolerance to moisture and oxygen
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent employs composite electrode structures where transition metal materials are combined with conductive matrices and functional coatings. The negative electrode uses transition metal or alloy materials, while the positive electrode combines host materials with transition metal compounds, creating composite structures that optimize both capacity and stability simultaneously

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs protective coatings and sealed structures that create an inert environment for the electrode materials, protecting them from moisture and oxygen exposure during manufacturing and operation. This approach maintains manufacturing simplicity while significantly improving tolerance to environmental factors

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a stable, non-flammable, and cost-effective battery with improved processing convenience, high tolerance to moisture and oxygen, and excellent cycle performance, reducing manufacturing complexity and costs while avoiding dendrite issues.

Implementation Method 1

The electrolyte is disposed between the positive electrode and the negative electrode

Methodology Applied
Scientific EffectIon transfer: Electrolyte

Implementation Method 2

a rechargeable transition metal battery includes a negative electrode, a positive electrode and an electrolyte

Methodology Applied
Scientific EffectElectrochemical reaction: Battery (electricity)

Data Source

PatentUS11848445B2Rechargeable transition metal battery
Publication Date: 2023.12.19 NATIONAL TSING HUA UNIVERSITY
  • US11848445B2 patent drawing
  • US11848445B2 patent drawing
  • US11848445B2 patent drawing

AI summary

A rechargeable transition metal battery includes a negative electrode, a positive electrode and an electrolyte. The negative electrode includes a negative electrode material which is a transition metal or an alloy of the transition metal. The positive electrode is electrically connected to the negative electrode and includes a host material and a positive electrode material. The host material includes a carbon. The positive electrode material is connected to the host material, and the positive electrode material is a compound of a metal, an elemental chalcogen or an elemental halogen. The electrolyte is disposed between the positive electrode and the negative electrode.