Transparent Ceramic Optics via Material Jet Printing

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Solution Overview

Problem

Conventional techniques for fabricating optics for laser gain media face challenges such as unstable optical mode, thermal lensing, optical distortion, reduced efficiency, and limited dimensionality, particularly in achieving precise control over compositional and structural features, which restrict their performance and scalability.

Innovation Solution

The method involves material jetting an ink comprising ceramic particles and a solvent to form a green body, which is then processed into a transparent ceramic optic with tunable spatial composition and layer thickness, enabling the creation of complex geometries and small feature sizes through precise control of droplet size, velocity, and composition, using optimized rheological properties and nozzle configurations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional fabrication techniques are used to produce optics, then the optics can be manufactured with current technology, but the optical mode becomes unstable and thermal lensing occurs

Engineering Contradiction:
Improveoptical mode stabilityVSAvoidcompositional and structural control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The optic is fabricated as multiple thin layers (each less than 50 microns thick) deposited sequentially through material jet printing. This segmentation allows precise compositional control in each layer while maintaining overall optical stability, resolving the contradiction between manufacturing precision and optical reliability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different layers are assigned different dopant compositions and concentrations tailored to specific functional requirements. This local quality approach enables optimization of each layer's properties to prevent thermal lensing and stabilize optical mode, while maintaining high manufacturing precision through controlled material deposition

Inventive Principle:
Principle #3Local quality

2Manufacturing precision

If conventional fabrication techniques are used, then manufacturing is simpler, but the feature sizes are large (>100 μm to millimeter) and dimensions are limited

Engineering Contradiction:
Improvefeature size controlVSAvoidfabrication complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention transitions from conventional bulk fabrication to layered additive manufacturing, adding the dimension of vertical layering. This enables precise control of feature sizes down to micrometer scale while maintaining ease of manufacture through automated material jet printing processes that deposit layers sequentially

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

Nanoparticles are pre-synthesized and dispersed in liquid vehicles to form printable inks with controlled rheological properties. This preliminary preparation enables precise deposition of small features through material jet printing, while the automated layer-by-layer construction maintains manufacturing simplicity despite the precision requirements

Inventive Principle:
Principle #10Preliminary action

3Productivity

If conventional fabrication techniques are used, then the production process is established, but efficiency is reduced and parasitic oscillations occur

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidoptical performance stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention changes key parameters including layer thickness (reduced to less than 50 microns), dopant concentration gradients, and material composition. These parameter changes eliminate parasitic oscillations and improve optical efficiency while maintaining productive manufacturing through automated material jet printing processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The optic is constructed as a composite structure with multiple layers containing different ceramic materials, dopants, and compositions. This composite approach maximizes manufacturing efficiency by enabling parallel optimization of each layer's properties while the automated deposition process maintains high productivity

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach stabilizes the optical mode, minimizes thermal lensing, maximizes efficiency, and reduces parasitic oscillations, allowing for the production of optics with smaller dimensions and improved performance compared to conventional methods, including the ability to fabricate thin layers and complex structures.

Implementation Method 1

The ink is physically characterized as having a density, surface tension, and viscosity configured to enable material jetting of the ink in contained, sequential droplets

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 2

The ink is physically characterized as having a density, surface tension, and viscosity configured to enable material jetting of the ink

Methodology Applied
Scientific EffectViscosity: Viscometer

Implementation Method 3

The resulting structure is densified to remove residual porosity and to form the final optic

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS20230110835A1Transparent ceramics fabricated by material jet printing
Publication Date: 2023.04.13 LAWRENCE LIVERMORE NAT SECURITY LLC
  • US20230110835A1 patent drawing
  • US20230110835A1 patent drawing
  • US20230110835A1 patent drawing

AI summary

A method for forming a transparent ceramic, in accordance with one embodiment, includes forming a green body by material jetting an ink, and processing the green body to form the ceramic to transparency. A product, in accordance with one embodiment, includes an ink for forming a transparent ceramic. The ink is physically characterized as having a density, surface tension, and viscosity configured to enable material jetting of the ink in contained, sequential droplets having a volume in the range of about 1 picoliter to about 1 nanoliter when jetted from a nozzle having an inner diameter in the range of about 10 microns to about 300 microns. A product, in accordance with another embodiment, includes a transparent ceramic, at least a portion of the transparent ceramic having layers of less than 50 microns per layer with physical characteristics of formation by material jetting.