Transparent Electroconductive Layer Moisture Resistance via Grain Boundary Segmentation

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Solution Overview

Problem

The existing light-transmitting electroconductive layers, particularly those with crystalline structures, face challenges in achieving low moisture permeability, which is essential for applications in touch panels, solar cells, and other devices, as they tend to have high moisture permeability, compromising their performance in harsh environments.

Innovation Solution

A transparent electroconductive layer is designed with a specific structure featuring a first and second grain boundary system where the second grain boundary branches from an intermediate portion of one first grain boundary to an adjacent one, creating a longer path for water to traverse, thereby enhancing moisture permeability resistance, and utilizing a tin-containing oxide material for excellent transparency and conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a crystalline transparent electroconductive layer is used to achieve low resistance properties, then electrical conductivity is improved, but moisture permeability increases

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmoisture permeability
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent segments the continuous grain boundaries into discontinuous sections by introducing second grain boundaries that branch from first grain boundaries. This segmentation creates a tortuous path for moisture penetration while maintaining the crystalline structure's electrical conductivity benefits.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces a new dimensional aspect to grain boundary configuration by adding second grain boundaries that branch perpendicular to the thickness direction, transforming the simple linear grain boundaries into a three-dimensional network structure that effectively blocks moisture paths.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Strength

If grain boundaries extend from upper surface to lower surface to provide structural continuity, then structural integrity is improved, but moisture permeability increases

Engineering Contradiction:
Improvestructural integrityVSAvoidmoisture permeability
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent segments the continuous grain boundaries into discontinuous sections by introducing second grain boundaries that branch from first grain boundaries. This segmentation creates a tortuous path for moisture penetration while maintaining the crystalline structure's electrical conductivity benefits.

Inventive Principle:
Principle #1Segmentation

Data Source

PatentUS11676739B2Transparent electroconductive layer, transparent electroconductive sheet, touch sensor, light control element, photoelectric conversion element, heat ray control member, antenna, electromagnetic wave shield member, and image display device
Publication Date: 2023.06.13 NITTO DENKO CORP
  • US11676739B2 patent drawing
  • US11676739B2 patent drawing
  • US11676739B2 patent drawing

AI summary

A transparent electroconductive layer 3 includes a first main surface 5 and a second main surface 6 facing each other in a thickness direction. The transparent electroconductive layer 3 is a single layer extending in a plane direction perpendicular to the thickness direction. The transparent electroconductive layer 3 has a plurality of crystal grains 4, a plurality of first grain boundaries 7 partitioning the plurality of crystal grains 4 and having each of one end edge 9 and another end edge 10 in the thickness direction open in each of the first main surface 5 and the second main surface 6, and a second grain boundary 8 branching from a first intermediate portion 11 of one first grain boundary 7A and reaching a second intermediate portion 12 of another first grain boundary 7B.