Transparent Electrode Transfer Printing for Low Surface Roughness

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Solution Overview

Problem

Existing methods for manufacturing transparent electrodes with patterned metal nanostructures face challenges in achieving low surface roughness, which affects the quality of subsequent functional layers and device performance in applications like solar cells, LEDs, and electronic sensors.

Innovation Solution

A method involving coating a smooth conductive material on a substrate, followed by screen printing and applying a surfactant-modified composite conductive material, and then using a liquid substrate for film transfer printing to embed the conductive materials, ensuring a low surface roughness and high bonding force for successful transfer printing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If screen printing is used to prepare transparent electrode with patterned metal nanostructure, then manufacturing cost is reduced and large area is achieved, but surface roughness increases

Engineering Contradiction:
Improvemanufacturing costVSAvoidsurface roughness
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent divides the electrode preparation into multiple layers: a smooth base layer (first conductive layer) and a patterned screen-printed layer (second conductive layer). The base layer provides the smooth surface, while the screen-printed layer provides the pattern and conductivity, resolving the contradiction between low cost and low roughness by segmenting the functional requirements across different layers.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies a smooth conductive base layer before screen printing the patterned layer. This preliminary action of creating a smooth foundation ensures that the subsequent screen-printed pattern does not inherit the roughness issues, allowing cost-effective screen printing while maintaining overall surface smoothness.

Inventive Principle:
Principle #10Preliminary action

2Area of stationary object

If screen printing is used to prepare transparent electrode, then large area is achieved, but surface roughness increases affecting subsequent functional layers

Engineering Contradiction:
Improvelarge areaVSAvoidsurface roughness
Core Design Contradiction:
Area of stationary objectVSManufacturing precision

Solution Approach 1:

The electrode is segmented into a smooth base layer and a patterned top layer. The base layer covers the entire large area with uniform smoothness, while the screen-printed pattern is applied only where needed, maintaining large area coverage without compromising overall surface quality.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the electrode have different properties: the base layer has uniform smooth conductivity across the entire large area, while the screen-printed pattern provides localized conductivity enhancement only in specific patterned regions, allowing large area coverage with controlled local roughness.

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If high surface roughness electrode is used, then manufacturing is simpler, but preparation quality of upper functional layers is affected

Engineering Contradiction:
Improveelectrode manufacturing simplicityVSAvoidfunctional layers preparation quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The electrode structure is segmented into a smooth base layer that provides the quality foundation for subsequent functional layers, and a separate patterned conductive layer. This segmentation ensures that the functional layers are deposited on a smooth surface while the conductive pattern is applied independently through screen printing.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The smooth base layer is prepared in advance before applying the screen-printed pattern and subsequent functional layers. This preliminary creation of a smooth surface ensures that all subsequent layers can be deposited with high quality, while the overall manufacturing remains simple due to the use of screen printing for the conductive pattern.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in transparent electrodes with remarkably low surface roughness, improved electrical conductivity, and high transparency, enhancing the performance and industrialization potential for various photoelectric devices.

Implementation Method 1

applying a liquid B substrate 5 material to the upper surface of the composite conductive material 4 treated in step S3 such that the overall lower conductive materials including the conductive material 2, the screen-printed pattern 3 and the composite conductive material 4 are all embedded in the B substrate 5 material

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

applying a liquid B substrate 5 material to the upper surface of the composite conductive material 4 treated in step S3 such that the overall lower conductive materials including the conductive material 2, the screen-printed pattern 3 and the composite conductive material 4 are all embedded in the B substrate 5 material

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 3

applying a layer of a surfactant-modified composite conductive material 4 by blade coating to the upper surface of the screen-printed pattern 3 treated in step S2

Methodology Applied
Scientific EffectSurfactant modification: Surfactant

Data Source

PatentUS12119138B2Method for manufacturing transparent electrode with low surface roughness
Publication Date: 2024.10.15 NANJING UNIV OF POSTS & TELECOMM
  • US12119138B2 patent drawing
  • US12119138B2 patent drawing

AI summary

A method for manufacturing a transparent electrode with a low surface roughness, in particular a method for preparing a large-area, low-cost and patterned transparent electrode using the screen-printing technology, which focuses on solving the problem of a high roughness of a screen-printed pattern. First, a substrate is coated with a layer of a smooth conductive material, then screen printing is performed to obtain a conductive pattern, and finally, a layer of a surfactant-modified composite conductive material is applied and film transfer printing is performed to obtain a transparent electrode with a low surface roughness. The transparent electrode prepared by the method retains a smooth surface of the original substrate after peeling, which has a remarkably low surface roughness and a significantly increased success rate of film transfer printing, and can be directly applied to various photoelectric devices, such as solar batteries, LEDs, flat panel displays and electronic sensors.