Transparent Liquid Composition Using Specific Surfactant Ratios

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Solution Overview

Problem

Current non-alcohol fragrance products with water as the main solvent face challenges in achieving a high perfume concentration while maintaining transparency, due to difficulties in solubilizing and emulsifying perfumes, often resulting in a cloudy appearance and limited usage.

Innovation Solution

A transparent liquid composition is achieved by using PEG-40 Hydrogenated Castor Oil and PPG-26-Buteth-26 as main solubilizers, along with a surfactant having an IOB value of 0.70-1.20 as an auxiliary solubilizer, at specific blending ratios, to stabilize a high concentration of perfumes in water without substantial ethyl alcohol content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If water is used as the main solvent to avoid oiliness and meet safety concerns, then consumer safety and comfort are improved, but the ability to stably dissolve high concentration of perfume deteriorates

Engineering Contradiction:
Improveethyl alcohol sensitivityVSAvoidperfume concentration
Core Design Contradiction:
Object-affected harmful factorsVSQuantity of substance

Solution Approach 1:

The patent introduces a specific surfactant system (main solubilizer and auxiliary solubilizer) as an intermediary between water and perfume. This surfactant system enables high concentration of perfume to be stably dissolved in water without ethyl alcohol, resolving the contradiction between safety (no ethyl alcohol) and perfume concentration capability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical parameters of the solubilizer system by specifying precise IOB values (0.70-1.20 for auxiliary solubilizer, 2000-5000 for main solubilizer) and blending ratios (0.03-0.60 for auxiliary to main solubilizer). These parameter optimizations enable stable high-concentration perfume dissolution in water-based formulations.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If surfactants are increased to improve perfume solubilization in water, then perfume concentration is improved, but stickiness and cloudiness worsen

Engineering Contradiction:
Improveperfume concentrationVSAvoidstickiness and cloudiness
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by differentiating the functions of two surfactant components: the main solubilizer (PEG-40 Hydrogenated Castor Oil with specific IOB value) handles bulk solubilization, while the auxiliary solubilizer (with IOB value 0.70-1.20) provides targeted assistance. This division of labor achieves high perfume concentration without excessive stickiness or cloudiness.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses a composite surfactant system combining PEG-40 Hydrogenated Castor Oil with specific auxiliary surfactants (IOB value 0.70-1.20) in controlled ratios. This composite approach provides synergistic effects that enable high perfume solubilization while maintaining transparency and reducing stickiness compared to single surfactant systems.

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If perfume concentration is increased to meet consumer demand for fragrance intensity, then fragrance performance is improved, but appearance transparency deteriorates

Engineering Contradiction:
Improveperfume concentrationVSAvoidappearance transparency
Core Design Contradiction:
Quantity of substanceVSIllumination intensity

Solution Approach 1:

The patent optimizes the IOB values and blending ratios of the surfactant system to achieve a critical balance point where high perfume concentration (3-20% by mass) can be maintained while preserving transparency. The specific parameter ranges (auxiliary solubilizer IOB: 0.70-1.20, main solubilizer IOB: 2000-5000, blending ratio: 0.03-0.60) ensure both fragrance intensity and appearance quality.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables the stable solubilization of a high concentration of perfumes in water, ensuring a transparent and uniform composition that avoids cloudiness and sedimentation, thus meeting consumer preferences for both safety and fragrance intensity.

Implementation Method 1

having PEG-40 Hydrogenated Castor Oil and PPG-26-Buteth-26 as a main solubilizer

Methodology Applied
Scientific EffectSolubilization: Solvation

Implementation Method 2

a surfactant having an IOB value of 0.70-1.20 as an auxiliary solubilizer

Methodology Applied
Scientific EffectEmulsification: Emulsion

Data Source

PatentUS12036308B2Transparent liquid composition
Publication Date: 2024.07.16 SHISEIDO CO LTD
  • US12036308B2 patent drawing
  • US12036308B2 patent drawing

AI summary

A transparent liquid composition that does not substantially contain ethyl alcohol, contains water as the main solvent, and has a high concentration of perfume is provided.The transparent liquid composition comprises: (a) 3-20% by mass of a perfume component; (b) a hydrogenated castor oil to which 30-60 moles of polyoxyethylene is added; (c) an alkanol obtained by addition polymerization of 20-30 moles of polyoxyprolylene and 20-30 moles of polyoxyethylene; (d) one type or more of a surfactant having an Inorganic-value/Organic-value of 0.70-1.20; and (e) 40% by mass or greater of an aqueous component other than ethyl alcohol, wherein the blending ratio (d/(b+c)) of the component (d) to the sum of the blending amounts of the components (b) and (c) is 0.03-0.60, and ethyl alcohol is not substantially contained.