Transparent Rubber Composition Abrasion Resistance

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Solution Overview

Problem

Current transparent rubber compositions for applications like shoe soles lack sufficient abrasion resistance while maintaining transparency and mechanical properties, particularly in sport shoes where lower abrasion resistance is required.

Innovation Solution

A curable transparent rubber composition comprising 35-60 wt.% of synthetic isoprene polymers and 35-60 wt.% of transparent polymers with similar refractive indices, along with a curing agent and additives, including 1-4 wt.% of polyalkenamers, to achieve haze less than 30% and total light transmission over 80%, enhancing abrasion resistance and transparency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional transparent rubber compositions are used, then transparency is achieved, but abrasion resistance is insufficient

Engineering Contradiction:
Improveabrasion resistanceVSAvoidtransparency
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent uses a composite material system consisting of polyisoprene rubber (providing transparency and rubber elasticity) combined with EAODM polymer (providing abrasion resistance). This composite approach allows both transparency and improved abrasion resistance to be achieved simultaneously, resolving the contradiction between these two properties.

Inventive Principle:
Principle #40Composite materials

2Strength

If carbon black and high amounts of additives are added to improve mechanical properties, then strength is improved, but transparency is lost

Engineering Contradiction:
Improvemechanical propertiesVSAvoidtransparency
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent extracts and eliminates carbon black and other opaque additives from the composition. Instead, it uses the EAODM polymer which provides the necessary mechanical properties (tear resistance and abrasion resistance) without compromising transparency, thus taking out the harmful opaque components while retaining beneficial properties.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the compositional parameters by using a specific ratio of polyisoprene to EAODM polymer (with EAODM content optimized between 5-50 phr). This parameter optimization allows achieving adequate mechanical strength without adding opaque fillers, maintaining transparency while improving performance.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If existing transparent rubber formulations are used, then good transparency is achieved, but abrasion resistance remains insufficient for sport shoes

Engineering Contradiction:
Improveabrasion resistanceVSAvoidcomposition formulation
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The EAODM polymer serves multiple functions simultaneously: it provides abrasion resistance, tear resistance, and maintains transparency. This multi-functionality simplifies the overall formulation complexity while achieving multiple performance requirements, particularly for sport shoe applications where abrasion resistance is critical.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved abrasion resistance, maintaining high transparency and mechanical properties, making it suitable for sport shoes and other applications with enhanced durability and aesthetic appeal.

Implementation Method 1

A cured transparent rubber composition is a material which is tough while exhibiting rubber behavior

Methodology Applied
Scientific EffectElasticity: Elasticity

Implementation Method 2

through which visible light passes... total transmittance greater than 80%, with haze below 30%... Component (a): from 35-60 wt.% of one or more synthetic isoprene polymers having a refractive index of between 1.500 to 1.525 at 23°C; Component (b) from 35-60 wt.% of one or more transparent polymers different from isoprene polymers wherein the difference between the refractive indices of component (a) and (b) is 0.100 or less

Methodology Applied
Scientific EffectLight transmission: Light

Data Source

PatentEP3416796B1A curable transparent rubber composition, a cured transparent rubber composition made thereof, and manufacturing process for the same
Publication Date: 2019.12.25 CARIFLEX PTE LTD
  • EP3416796B1 patent drawing
  • EP3416796B1 patent drawing

AI summary

The present disclosure provides a solid curable transparent rubber composition containing one or more synthetic isoprene polymer, one or more transparent polymer, one or more curing agent, additives that do not influence transparency and one or more polyalkenamers. The solid curable transparent rubber composition, once cured, has a haze of less than 30% and a total light transmission of more than 80%. The disclosure further provides a cured transparent rubber composition made thereof, and a manufacturing process for the cured composition. The present disclosure also provides an article including the rubber composition, in particular shoes with transparent soles.