Transparent Silicone Elastomer Dental Impression Composition

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Solution Overview

Problem

Conventional dental impression materials are opaque due to reinforcing fillers and additives, making it difficult for dentists to visually confirm positioning and air bubble removal, and their viscosity issues complicate manual dispensing.

Innovation Solution

A silicone elastomer composition without reinforcing fillers, using a combination of alkenyl group-containing organopolysiloxanes of differing molecular weights to achieve suitable flowability and transparency, ensuring mechanical strength and transparency in both uncured and cured states.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If reinforcing fillers such as silica are added to the base polymer, then rubber strength is improved, but transparency deteriorates

Engineering Contradiction:
Improverubber strengthVSAvoidtransparency
Core Design Contradiction:
StrengthVSIllumination intensity

Solution Approach 1:

The invention extracts and removes reinforcing fillers such as silica from the composition. By eliminating these opaque fillers, the material achieves high transparency while maintaining sufficient mechanical strength through the optimized polymer network structure formed by the specific organopolysiloxane composition.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical composition parameters by specifying precise ranges for different organopolysiloxane components (Component A: 10-100 parts, Component B: 10-50 parts, Component C: 5-30 parts). This parameter optimization allows the material to achieve both adequate strength without fillers and high transparency.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If viscosity is reduced to improve flowability, then ease of operation is improved, but mechanical strength deteriorates

Engineering Contradiction:
ImproveflowabilityVSAvoidmechanical strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The invention optimizes viscosity parameters by combining organopolysiloxanes of different molecular weights and viscosities. Component A provides base viscosity control, while Components B and C adjust the overall flow characteristics. This parameter balancing achieves suitable flowability for dental impressions while maintaining cured mechanical strength.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite polymer system combining three different organopolysiloxane components with distinct molecular weight ranges and viscosity characteristics. This composite structure allows the uncured material to have appropriate flowability while the cured network achieves sufficient mechanical strength.

Inventive Principle:
Principle #40Composite materials

3Strength

If viscosity is increased to improve structural stability, then strength is improved, but ease of operation deteriorates

Engineering Contradiction:
Improvestructural stabilityVSAvoidmanual dispensing
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The invention adjusts viscosity parameters within an optimal range (100-500 cP at 25°C) by controlling the ratios of Components A, B, and C. This parameter optimization ensures the material is thick enough to maintain structural stability but thin enough for easy manual dispensing from cartridges.

Inventive Principle:
Principle #35Parameter changes

4Adaptability or versatility

If additives are added to adjust hardness and flowability, then adaptability is improved, but compatibility deteriorates causing opacity

Engineering Contradiction:
Improvehardness adjustmentVSAvoidcompatibility
Core Design Contradiction:
Adaptability or versatilityVSIllumination intensity

Solution Approach 1:

The invention removes traditional plasticizer additives that cause compatibility issues and opacity. Instead, it uses the inherent viscosity and molecular weight characteristics of the organopolysiloxane components themselves to adjust hardness and flowability, maintaining full compatibility and transparency.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides high transparency, allowing visual confirmation during application, suitable viscosity for easy handling, and excellent mechanical strength, enhancing the precision and efficiency of dental impressions.

Implementation Method 1

a silicone elastomer composition which ensures a sufficient strength as a dental impression material and has a flowability suitable for taking a dental impression can be obtained by using in combination a plurality of alkenyl group-containing organopolysiloxanes of differing molecular weights

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentEP3058932B1Silicone elastomer composition for use as dental impression material
Publication Date: 2023.07.26 SHIN ETSU CHEMICAL CO LTD

AI summary

A silicone elastomer composition adapted for use as a dental impression material includes (A) a high-viscosity alkenyl group-containing organopolysiloxane, (B) a low-viscosity alkenyl group-containing organopolysiloxane, (C) a gum-like alkenyl group-containing organopolysiloxane, (D) a silicone resin, (E) an organohydrogenpolysiloxane, (F) a hydrosilylation catalyst and (G) a filler, and has a viscosity at 23°C of at least 100 Pa·s and less than 300 Pa·s. The composition has a high transparency and a flowability suitable for taking dental impressions, and provides a sufficient strength when cured.