Transparent Substrate Antifouling Layer for Creamy Product Removal

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Solution Overview

Problem

Instrument panel cover glass with a fine concavo-convex structure for antiglare properties lacks sufficient antifouling properties, particularly in removing creamy products like hand cream from the water-repellent film described in prior art.

Innovation Solution

An antifouling layer-provided transparent substrate with a divalent group represented by -(OCF2)v(OCF2CF2)w-, where v and w are integers of at least 1, and a specific surface roughness and fluorine content, combined with a reactive silyl group, to enhance antiglare and antifouling properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a water-repellent film is formed using a hydrolyzable silane compound having a perfluoroalkylene group or a fluorinated polyether group, then water repellency and abrasion resistance are improved, but the removability of creamy products such as hand cream is insufficient

Engineering Contradiction:
Improvewater repellency and abrasion resistanceVSAvoidremovability of creamy products
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent changes the chemical composition parameters of the antifouling layer by introducing a specific divalent group -(OCF2)v(OCF2CF2)w- with controlled v and w values (v+w≥2), and adjusts the surface roughness parameters (Ra and RSm) to achieve optimal balance between water repellency and creamy product removability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite antifouling layer combining multiple functional groups: the divalent group -(OCF2)v(OCF2CF2)w- for water/oil repellency, the reactive silyl group for adhesion to the transparent substrate, and controls surface morphology through the antiglare layer, achieving multifunctional performance

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If a fine concavo-convex structure is provided on the surface to obtain antiglare properties, then visibility is improved, but the antifouling properties especially removability of creamy products is insufficient

Engineering Contradiction:
Improveantiglare propertiesVSAvoidremovability of creamy products
Core Design Contradiction:
Illumination intensityVSEase of operation

Solution Approach 1:

The patent segments the surface structure into two distinct functional layers: the transparent substrate with fine concavo-convex structure for antiglare properties, and the separate antifouling layer with specific surface roughness (Ra: 0.01-0.15 μm, RSm: 0.5-5.0 μm) for antifouling performance, allowing each layer to optimize its specific function

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies different surface quality characteristics to different layers: the transparent substrate maintains the fine concavo-convex structure for light scattering (antiglare), while the antifouling layer has a specific combination of roughness parameters (low Ra, moderate RSm) optimized for creamy product removability

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The substrate achieves excellent antiglare and antifouling properties, particularly in the removability of creamy products, by optimizing the surface roughness and fluorine content of the antifouling layer.

Implementation Method 1

a water-repellent film formed by using a hydrolyzable silane compound having a perfluoroalkylene group or a fluorinated polyether group

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Implementation Method 2

a compound having a divalent group represented by -(OCF2)v(OCF2CF2)w- (where v and w are each independently an integer of at least 1) and a reactive silyl group

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentEP3978232B1Transparent substrate with antifouling layer
Publication Date: 2024.06.05 AGC INC
  • EP3978232B1 patent drawingFigure 1~3
  • EP3978232B1 patent drawing
  • EP3978232B1 patent drawing

AI summary

To provide an antifouling layer-provided transparent substrate, which is excellent in antiglare and antifouling properties, especially in removability of a creamy product such as hand cream. An antifouling layer-provided transparent substrate, containing a transparent substrate and an antifouling layer provided as the top surface layer on one main surface of the transparent substrate, where the antifouling layer has a divalent group represented by -(OCF2)v(OCF2CF2)w- (where v and w are each independently an integer of at least 1), and the surface of the antifouling layer is such that the mean width RSm of the elements and the arithmetical mean roughness Ra satisfy RSm≧Ra×100+5.