Transparent Substrate with Resin Layer for Solvent Crack Resistance

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Solution Overview

Problem

Conventional transparent substrates used in display devices and solar cells face challenges with solvent durability, toughness, and heat resistance, particularly when exposed to solvents like acetone, leading to solvent cracks and insufficient impact resistance.

Innovation Solution

A transparent substrate is developed with an inorganic glass layer coated on both sides with a resin layer containing a specific resin compound with a weight-average molecular weight of 8×10^4 to 100×10^4, featuring a specific molecular structure and a coupling agent layer for enhanced adhesion and solvent resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a resin layer is formed on glass surface to improve flexibility and handleability, then weight reduction and flexibility are achieved, but solvent durability deteriorates and solvent cracks occur

Engineering Contradiction:
ImprovehandleabilityVSAvoidsolvent durability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent changes the molecular weight parameter of the resin compound to a specific range (8×10^4 to 100×10^4) to simultaneously achieve flexibility and solvent durability. This parameter optimization allows the resin layer to maintain both mechanical flexibility for handleability and chemical resistance against solvents during display device manufacturing.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure by forming a resin layer on the glass substrate surface. This composite material combines the mechanical strength and rigidity of glass with the flexibility and solvent resistance properties of the specially formulated resin compound, resolving the contradiction between handleability and solvent durability.

Inventive Principle:
Principle #40Composite materials

2Weight of moving object

If glass substrate is thinned to achieve weight reduction, then weight decreases and flexibility improves, but impact resistance becomes insufficient

Engineering Contradiction:
ImproveweightVSAvoidimpact resistance
Core Design Contradiction:
Weight of moving objectVSStrength

Solution Approach 1:

The patent employs a composite structure combining thin glass substrate with a resin layer. The resin layer acts as a protective coating that enhances impact resistance while allowing the glass to remain thin for weight reduction. This composite approach enables the substrate to achieve both lightweight and high impact resistance properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The resin layer serves as a pre-applied protective cushion on the glass surface that absorbs and distributes impact forces before they can cause damage to the thin glass substrate. This beforehand cushioning effect allows the thin glass to maintain sufficient impact resistance despite its reduced thickness.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Ease of operation

If conventional resin layer is used to provide flexibility, then flexibility is achieved, but heat resistance becomes insufficient

Engineering Contradiction:
ImproveflexibilityVSAvoidheat resistance
Core Design Contradiction:
Ease of operationVSTemperature

Solution Approach 1:

The patent optimizes the molecular weight parameter of the resin compound to a specific high range (8×10^4 to 100×10^4), which simultaneously improves both flexibility and heat resistance. This parameter change ensures the resin layer maintains its mechanical flexibility while exhibiting sufficient thermal stability for display device manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP2492090B1Transparent substrate
Publication Date: 2018.03.21 NITTO DENKO CORP
  • EP2492090B1 patent drawingFigure 1(a)~1(c)
  • EP2492090B1 patent drawing
  • EP2492090B1 patent drawing

AI summary

The present invention provides a transparent substrate excellent in solvent crack resistance, toughness, heat resistance, and flexibility. A transparent substrate according to an embodiment of the present invention includes: an inorganic glass; and a first resin layer placed on at least one side of the inorganic glass, wherein: the first resin layer contains a resin compound having a weight-average molecular weight in terms of polystyrene of 8×104 to 100×104; and no solvent crack occurs when a mixed solvent containing 20 wt% to 95 wt% of at least one kind of solvent selected from the group consisting of acetone, N-methylpyrrolidone, dimethyl sulfoxide, and N,N-dimethylformamide is brought into contact with the substrate.