Treated PET Feedstocks for Mixed-Composition Chemical Recycling

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Solution Overview

Problem

Existing recycling methods limit the use of recycled plastics to similar compositions, restricting their application in creating new materials.

Innovation Solution

The development of particulate plastic solids comprising specific compositions, such as greater than 70% polyethylene terephthalate, controlled moisture and halogen content, and inclusion of polyolefins and nylons, allows for the creation of new materials with varied chemical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If traditional recycling methods are used to process mixed plastic waste, then the recycling process is simple and maintains original plastic composition, but the recycled plastics are limited to creating new articles of the same composition only

Engineering Contradiction:
Improveapplication range of recycled plasticsVSAvoidrecycling process complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The recycling process is divided into multiple sequential separation stages, each targeting specific plastic types based on density differences. This segmentation allows complex mixed plastic waste to be systematically broken down into distinct streams (PET, polyolefins, PVC, etc.), enabling versatile applications of each separated fraction while managing complexity through modular processing steps

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The process utilizes changes in physical parameters (density, solubility, phase behavior) to separate different plastic types. By adjusting parameters such as liquid density in flotation tanks or temperature in fractionation steps, the system achieves selective separation of plastic components, transforming the original mixed composition into purified streams suitable for diverse new applications

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If mechanical sorting methods are used to separate plastics by composition, then the sorting precision is high, but the process requires multiple stages and becomes complex

Engineering Contradiction:
Improveplastic separation precisionVSAvoidsorting system complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical sorting systems with processes based on physical-chemical properties. Instead of relying on mechanical optical sorters and multiple mechanical separation devices, the system uses density-based flotation, solubility-based extraction, and phase separation techniques to achieve high-precision plastic separation with simpler equipment configurations

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The recycling system is designed as an integrated multi-functional process that combines several separation mechanisms (flotation, fractionation, filtration) into a unified workflow. This universal approach handles multiple plastic types simultaneously through a single coordinated system rather than requiring separate specialized devices for each plastic type, reducing overall complexity while maintaining high separation precision

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentUS12454604B2Treated waste plastic materials
Publication Date: 2025.10.28 EASTMAN CHEM CO
  • US12454604B2 patent drawing
  • US12454604B2 patent drawing
  • US12454604B2 patent drawing

AI summary

Isolated quantities of plastic solids having greater than 70% by weight polyethylene terephthalate (PET) also include a) from 0.1% to 10% by weight polyvinyl chloride (PVC), and a moisture content of less than 4% by weight, or b) from 0.05% to 10% or 0.1% to 4% by weight halogens, or c) from 0.1% to 4% by weight polyvinyl chloride (PVC), and at least 0.1% by weight of solid materials that do not phase change below 270° C. and 1 atm. The quantities of these solid plastics are suitable for use as feedstocks to various chemical recycling processes.