Treated TiO2 Pigment UV Stability and Anti-microbial Coating

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Solution Overview

Problem

Current titanium dioxide pigments used in paper laminates lack multi-functional properties such as reduced photoactivity and improved anti-microbial characteristics, which are essential for enhancing the durability and performance of decorative paper surfaces.

Innovation Solution

A treated titanium dioxide pigment is developed by applying a silicon compound and co-precipitated zinc oxide and alumina, which are added in specific weight percentages to the titanium dioxide core particles, enhancing their anti-microbial properties and light fastness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional titanium dioxide pigments are used in paper laminates, then opacity and whiteness are achieved, but photoactivity causes color change under UV exposure and lacks anti-microbial properties

Engineering Contradiction:
Improvelight fastnessVSAvoidphotoactivity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies a multi-layer coating structure where different materials are applied to different regions of the titanium dioxide particle surface. The silica layer is applied first as a base coating, followed by a zinc oxide and alumina layer. This localized multi-layer structure allows each material to perform its specific function: silica provides structural support and UV screening, while the zinc oxide and alumina outer layer provides photoactivity reduction and anti-microbial properties.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent creates a composite pigment particle consisting of a titanium dioxide core surrounded by multiple coating layers. The core TiO2 provides opacity and whiteness, while the silica intermediate layer provides structural stability and UV protection. The outer layer of co-precipitated zinc oxide and alumina provides photoactivity reduction and anti-microbial properties. This composite structure integrates multiple functions within a single pigment particle.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If multiple separate treatments are applied to titanium dioxide to achieve different properties, then functional improvements are made, but manufacturing complexity increases

Engineering Contradiction:
Improvemulti-functional propertiesVSAvoidmanufacturing process
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent combines multiple treatment steps into an integrated multi-layer coating process. The silica coating is applied in a first step, and the zinc oxide and alumina co-precipitation is applied in a second step. By merging these treatments into a sequential coating process rather than separate batch treatments, the patent achieves multi-functional properties while controlling manufacturing complexity through process integration.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent applies the silica coating as a preliminary layer before applying the zinc oxide and alumina layer. This preliminary action of silica coating prepares the surface for subsequent coating, provides structural foundation, and ensures proper adhesion of the outer functional layer. This sequential approach allows each layer to be optimized independently while maintaining overall process efficiency.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The treated pigment exhibits improved light fastness, reduced acid solubility, and enhanced anti-microbial properties, leading to increased durability and resistance against color change under UV exposure, while maintaining brightness and gloss.

Implementation Method 1

a first treatment of a silicon compound, such as silica, wherein the silicon compound is added in a single step

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 2

a second treatment comprising a co-precipitated zinc oxide and alumina

Methodology Applied
Scientific EffectCo-precipitation: Coprecipitation

Data Source

PatentEP2726672B8Treated inorganic pigments having reduced photoactivity and Anti-microbial properties and their use in paper slurries
Publication Date: 2016.08.24 THE CHEMOURS CO TT LLC

AI summary

The disclosure provides a paper slurry comprising a treated inorganic particle having reduced photoactivity and improved anti-microbial properties, wherein the treated inorganic pigment comprises: an inorganic core particle; a first treatment of a silicon compound, wherein the silicon compound is added in a single step; and a second treatment comprising a co-precipitated zinc oxide and alumina.