Tri-Layer Siloxane Adhesive for Stepped Wafer Processing

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Solution Overview

Problem

Existing temporary adhesive layers for wafer processing are inadequate in forming a uniform thickness on heavily stepped substrates, failing to provide a complete bond and are not easily removable, which hampers the manufacturing of thin wafers with TSV and bump interconnect structures.

Innovation Solution

A tri-layer temporary bonding arrangement consisting of a thermoplastic siloxane bond-free polymer, a thermoplastic organopolysiloxane polymer, and a thermosetting modified siloxane polymer is used, with the peripheral region of the intermediate layer removed to ensure direct contact between the outer layers, facilitating a stable bond and easy removal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a single-layer organic resin protective tape is used, then the wafer is protected during grinding, but the tape lacks sufficient strength and heat resistance for TSV forming and back surface processing

Engineering Contradiction:
Improvestrength and heat resistanceVSAvoidprotective capability during processing
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent employs a composite adhesive layer structure consisting of a first adhesive layer (siloxane-modified polymer) and a second adhesive layer (different polymer material) with distinct thicknesses and properties. This composite structure combines the heat resistance and bonding strength of siloxane-modified polymers with the protective characteristics of other polymer materials, achieving both high strength/heat resistance and reliable protective capability during various processing steps including TSV forming and back surface processing.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If existing temporary adhesive layers are used, then bonding is achieved, but uniform thickness cannot be formed on heavily stepped substrates

Engineering Contradiction:
Improveuniformity of adhesive layer thicknessVSAvoidapplicability to stepped substrates
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent applies local quality by creating a composite adhesive layer where the first adhesive layer (with higher viscosity and heat resistance) is positioned at the bottom near the support, while the second adhesive layer (with different properties) is positioned at the top near the wafer. This spatial differentiation of material properties allows the lower layer to fill gaps and steps effectively while the upper layer provides uniform bonding characteristics, achieving both uniform thickness on stepped substrates and broad adaptability.

Inventive Principle:
Principle #3Local quality

3Ease of operation

If existing temporary adhesive layers are used, then bonding is established, but easy removal is not achieved

Engineering Contradiction:
Improveease of removalVSAvoidbond durability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent utilizes parameter changes by selecting adhesive materials with specific glass transition temperatures (Tg) and bonding characteristics. The first adhesive layer uses siloxane-modified polymer with controlled Tg to provide strong bonding during processing, while the second adhesive layer is formulated with different thermal and chemical properties that enable easy removal after processing. This parameter differentiation between layers allows the system to exhibit strong bonding during use and easy removal afterward, resolving the contradiction between bond durability and ease of removal.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution allows for the formation of a uniform adhesive layer on stepped substrates, enabling the manufacture of thin wafers with improved heat resistance and ease of removal, enhancing productivity and handling of fragile wafers.

Implementation Method 1

a third temporary bond layer of thermosetting polymer comprising a modified siloxane polymer based layer

Methodology Applied
Scientific EffectThermal curing: Heat Treatment

Implementation Method 2

a second temporary bond layer of thermoplastic organopolysiloxane having a high degree of polymerization

Methodology Applied
Scientific EffectThermal adhesion: Heating

Data Source

PatentEP2657963B1Wafer-trilayer adhesive layer-support composite, wafer support with trilayer adhesive layer for use in wafer processing, trilayer adhesive layer for use in wafer processing, method of manufacturing said composite and method of manufacturing a thin wafer using said composite
Publication Date: 2017.09.06 SHIN ETSU CHEMICAL CO LTD
  • EP2657963B1 patent drawingFigure 1
  • EP2657963B1 patent drawing
  • EP2657963B1 patent drawing

AI summary

A wafer processing laminate is provided comprising a support (3), a temporary adhesive layer (2), and a wafer (1). The temporary adhesive layer (2) has a trilayer structure consisting of a first temporary bond layer (A) of thermoplastic siloxane bond-free polymer, a second temporary bond layer (B) of thermoplastic siloxane polymer, and a third temporary bond layer (C) of thermosetting modified siloxane polymer. In a peripheral region, the second layer (B) is removed so that the first layer (A) is in close contact with the third layer (C).