Triazine Compound Charge Balance OLED Efficiency

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Solution Overview

Problem

Existing organic optoelectronic devices face challenges in achieving balanced charge transport and stability, leading to limited luminous efficiency and lifespan in organic light emitting diodes.

Innovation Solution

A compound represented by Chemical Formula 1, which includes a triazine core linked with 3-dibenzofuranyl or 3-dibenzothiophenyl groups and a carbazole moiety, separates hole and electron transport moieties effectively, enhancing charge balance and stability, and a composition combining this compound with another for improved mobility and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic optoelectronic devices are used, then device simplicity is maintained, but charge transport balance and stability are insufficient

Engineering Contradiction:
Improvecharge transport balanceVSAvoidmolecular structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The compound is divided into distinct functional segments: a triazine core structure and separately attached hole transport moiety and electron transport moiety. This segmentation allows each segment to independently optimize its charge transport function, achieving balanced charge transport while maintaining a relatively simple overall molecular structure that can be synthesized through modular approaches.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite molecular structure by combining hole transport and electron transport moieties within a single compound framework. This composite approach enables both charge transport functions to coexist and balance each other within the same material, improving reliability without requiring multiple separate materials or complex device architectures.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional organic optoelectronic devices are used, then manufacturing process simplicity is maintained, but luminous efficiency and lifespan are limited

Engineering Contradiction:
Improveluminous efficiencyVSAvoidsynthesis complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The compound serves multiple functions simultaneously: it acts as both a hole transport material and an electron transport material, and also functions as an emitter in the organic light-emitting diode. This multi-functionality improves luminous efficiency by optimizing charge transport and recombination within a single material system, while the synthesis, though moderately complex, follows established organic chemistry protocols for triazine-based compounds.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Stability of the object's composition

If conventional organic optoelectronic devices are used, then device structure simplicity is maintained, but stability is insufficient

Engineering Contradiction:
Improvedevice stabilityVSAvoidcompound structure complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The compound incorporates specific local structural features: the triazine core provides structural rigidity and chemical stability, while the strategically positioned hole transport and electron transport moieties are placed at specific locations on the core. This local optimization of structure-function relationships enhances overall device stability without requiring complex overall molecular architectures.

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS11217756B2Compound for organic optoelectronic device, composition for organic optoelectronic device and organic optoelectronic device and display device
Publication Date: 2022.01.04 SAMSUNG SDI CO LTD
  • US11217756B2 patent drawing
  • US11217756B2 patent drawing
  • US11217756B2 patent drawing

AI summary

Disclosed are the compound for an organic optoelectronic device, the compound being represented by Chemical Formula 1, a composition for an organic optoelectronic device including the compound for an organic optoelectronic device, an organic optoelectronic device, and a display device.In Chemical Formula 1, each substituent is the same as defined in the specification.