Triazine Compound Electron Transport Material for OLED Lifetime

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Solution Overview

Problem

There is a need for new materials, particularly charge-transporting materials like electron-transporting and hole-blocking materials, to enhance the performance of organic electroluminescence devices in terms of lifetime, efficiency, and driving voltage.

Innovation Solution

A specific compound represented by formula (I) is used as a charge-transporting or charge-blocking material, specifically as an electron-transporting material, which is thermally stable and suitable for organic electroluminescence devices, potentially used in various organic electronic devices including OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electron-transporting materials are used in organic EL devices, then the devices can operate, but the lifetime is short and efficiency is low

Engineering Contradiction:
Improvedevice lifetimeVSAvoiddevice efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent modifies the molecular structure of electron-transporting materials by introducing specific substituents (R1-R6) on the triazine core, changing chemical parameters to achieve both long lifetime and high efficiency simultaneously. The systematic variation of aromatic hydrocarbon groups and heteroaryl groups optimizes electron mobility and stability parameters.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite molecular structures combining triazine core with various aromatic and heteroaryl groups, achieving synergistic effects that simultaneously improve device lifetime and efficiency. The composite structure integrates electron-transporting capability with thermal stability and electrochemical stability.

Inventive Principle:
Principle #40Composite materials

2Productivity

If high-performance electron-transporting materials are used, then efficiency improves, but driving voltage increases

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent optimizes the HOMO and LUMO energy levels of the electron-transporting materials through systematic structural modifications, achieving low driving voltage while maintaining high efficiency. The energy level parameters are tuned to match with common hole-transporting materials and emitters.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If new charge-transporting materials are developed, then device performance improves, but material synthesis complexity increases

Engineering Contradiction:
Improvedevice performanceVSAvoidmaterial synthesis
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent divides the electron-transporting material into a core triazine structure and modular substituent groups (R1-R6), allowing independent optimization of each segment. This segmentation enables systematic synthesis through standard organic chemistry reactions while maintaining high device performance.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound provides organic electroluminescence devices with improved performance characteristics such as long lifetime, high efficiency, and low driving voltage, and can be applied in multiple organic electronic applications beyond OLEDs.

Implementation Method 1

The 1,3,5-triazine compound can be used as an electron transport material

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

The compound can be used as a charge-transporting material or a charge-blocking material, preferably as an electron-transporting material and/or hole-blocking material

Methodology Applied
Scientific EffectHole blocking: Electrical Resistance

Implementation Method 3

When a voltage is applied to an organic electroluminescence device, holes are injected to an emitting layer from an anode and electrons are injected to an emitting layer from a cathode. In the emitting layer, injected holes and electrons are re-combined and excitons are formed.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20230120308A1Compound, material for an organic electroluminescence device and an organic electroluminescence device comprising the compound
Publication Date: 2023.04.20 IDEMITSU KOSAN CO LTD
  • US20230120308A1 patent drawing
  • US20230120308A1 patent drawing
  • US20230120308A1 patent drawing

AI summary

Specific compounds represented by formula (I), a material for an organic electroluminescence device comprising said specific compound, an organic electroluminescence device comprising said specific compound, an electronic equipment comprising said organic electroluminescence device and the use of said compounds in an organic electroluminescence device.