Organic Semiconductor Layer with Triazine Ring for OLED Stability

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Solution Overview

Problem

There is a need for organic semiconductor materials and devices with improved electron mobility and electrochemical stability to enhance the performance of organic light-emitting diodes (OLEDs), particularly for large-size flat panel displays, while maintaining low operating voltage and power consumption.

Innovation Solution

A compound with a specific chemical formula is used as a layer material in OLEDs, featuring an anellated aromatic or heteroaromatic ring structure that enhances electron transport characteristics, stability, and luminance efficiency, with a low operating voltage and minimal emissive contribution to the visible spectrum.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic semiconductor materials are used, then device structure is simple, but electron mobility is insufficient and electrochemical stability is poor

Engineering Contradiction:
Improveelectrochemical stabilityVSAvoidmolecular structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite molecular structures combining electron-transporting moieties (such as triazine rings, pyrimidine rings, or pyridine rings) with aromatic hydrocarbon groups (phenyl, naphthyl, anthryl groups). This composite approach integrates the electrochemical stability provided by the heterocyclic electron-transporting units with the structural framework of aromatic hydrocarbons, achieving both improved reliability and controlled complexity through deliberate molecular design

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces specific functional groups (electron-transporting moieties containing N, O, or S atoms) at strategic positions within the molecular structure. These localized functional regions provide enhanced electrochemical stability and electron mobility without requiring complete restructuring of the entire molecule, thus improving reliability while maintaining manageable structural complexity through targeted modifications

Inventive Principle:
Principle #3Local quality

2Productivity

If organic semiconductor layer is optimized for high efficiency, then luminance efficiency improves, but operating voltage increases and power consumption rises

Engineering Contradiction:
Improveluminance efficiencyVSAvoidpower consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent optimizes specific molecular parameters including the selection of electron-transporting moieties (triazine, pyrimidine, pyridine rings), the type of aromatic hydrocarbon groups (phenyl, naphthyl, anthryl), and their connectivity patterns. These parameter changes enable tuning of electron mobility and HOMO/LUMO energy levels to achieve high luminance efficiency at reduced operating voltages, thereby lowering power consumption while maintaining high productivity

Inventive Principle:
Principle #35Parameter changes

3Speed

If electron mobility is increased to improve device performance, then charge transport improves, but electrochemical stability may deteriorate

Engineering Contradiction:
Improveelectron mobilityVSAvoidelectrochemical stability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent creates composite molecular structures where electron-transporting moieties (providing high electron mobility through their heterocyclic ring systems with delocalized electrons) are combined with stable aromatic hydrocarbon frameworks (phenyl, naphthyl, anthryl groups). This composite design ensures that the electron mobility enhancement from the heterocyclic units is balanced by the electrochemical stability provided by the aromatic hydrocarbon portions, achieving both improved speed and reliability simultaneously

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS11462691B2Organic electronic device comprising an organic semiconductor layer
Publication Date: 2022.10.04 NOVALED GMBH
  • US11462691B2 patent drawing
  • US11462691B2 patent drawing
  • US11462691B2 patent drawing

AI summary

The present invention relates to compounds comprising a TAE-structure to which a substituted or unsubstituted triazine ring is directly bonded, for use as a layer material for electronic devices, and to an organic electronic device comprising the layer material, and a method of manufacturing the same.