Triazine Sunscreen Composition with Non-Ionic Surfactant

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Solution Overview

Problem

Current sunscreen compositions fail to provide stable high SPF protection over a sustained period using triazine compounds without additional UV-A or UV-B sunscreens, especially in fatty acid-containing oil-in-water emulsions, and often require high amounts of sunscreen agents, increasing costs.

Innovation Solution

A sunscreen composition comprising 0.05 to 15% of a triazine compound, 0.01 to 10% non-ionic surfactants with high HLB values, and a cosmetically acceptable base with 6 to 25% fatty acids, which includes additional UV-A or UV-B sunscreens, solubilizers, and photostabilizers to achieve high SPF values with reduced total organic sunscreen content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high amounts of UV-A and UV-B sunscreen agents are used to achieve high SPF, then sun protection factor is improved, but manufacturing cost increases

Engineering Contradiction:
Improvesun protection factorVSAvoidamount of sunscreen agents
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent changes the chemical parameters by using triazine compounds (specifically compounds of formula I with particular R1-R6 group configurations) instead of conventional sunscreen agents. This parameter change allows achieving high SPF with lower quantities of active ingredients

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite sunscreen system combining triazine compounds with specific non-ionic surfactants (having HLB 10-20) and fatty acids (C12-C22) in defined ratios. This composite formulation enhances the photoprotective efficiency per unit of active ingredient

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If triazine compounds are used without additional UV-A or UV-B sunscreens, then cost is reduced, but photostability and sustained protection are compromised

Engineering Contradiction:
Improvetotal sunscreen agent contentVSAvoidphotostability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent introduces non-ionic surfactants as intermediary substances that mediate between the triazine compound and the aqueous environment. These surfactants (with HLB 10-20) stabilize the triazine compound formulation, preventing degradation and ensuring sustained photoprotection without requiring additional UV filters

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention optimizes the concentration parameters of triazine compounds (0.1-10% w/w) and combines them with specific fatty acid chains (C12-C22) to achieve the desired photostability profile, allowing reduced total sunscreen content while maintaining protection

Inventive Principle:
Principle #35Parameter changes

3Reliability

If non-ionic surfactant is included in cosmetic base with fatty acids, then high SPF is achieved, but formulation complexity increases

Engineering Contradiction:
ImproveSPF valueVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The non-ionic surfactants in the patent perform multiple functions simultaneously: they act as emulsifiers for the fatty acid base, photostabilizers for the triazine compound, and SPF-enhancing agents. This multi-functionality reduces the need for separate additives, simplifying the overall formulation despite the high SPF achievement

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves SPF values higher than 20, with enhanced stability and reduced costs by utilizing low amounts of sunscreen agents, providing effective protection against UV-A and UV-B radiation while maintaining cosmetic properties.

Implementation Method 1

a non-ionic surfactant; selected from the group consisting of (a) fatty alcohol ethoxylates with saturated carbon chain and having HLB higher than 15.5; or (b) alkyl phenol ethoxylates having HLB higher than 15

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

Solar radiation includes ultraviolet (UV) radiation, wavelength of which is between 200 nm and 400 nm. Exposure of skin to UV-A (320 to 400 nm) and UV-B (290 to 320 nm) causes various problems

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentEP2879655B1A photostable sunscreen composition
Publication Date: 2019.12.04 UNILEVER NV
  • EP2879655B1 patent drawing
  • EP2879655B1 patent drawing
  • EP2879655B1 patent drawing

AI summary

The invention relates to a photostable sunscreen composition that not only provides enhanced sun protection by way of high SPF, but does that over sustained period of time after applying the composition on the skin. The present inventors have found that when a compound of the triazine group is used without additional UVA or UVB sunscreen, and a non-ionic surfactant is included in a cosmetic base comprising fatty acids, it is possible to achieve high SPF.