Triazinyl Organic Compounds for Charge Mobility and Stability

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Solution Overview

Problem

Current organic optoelectric devices face challenges in achieving high efficiency and long lifespan, particularly in large-size flat panel displays, due to limitations in hole and electron mobility and electrochemical stability of organic materials.

Innovation Solution

A dimer-shaped or ditriazine-shaped compound with triazinyl groups bonded at meta-positioned phenyl linkers is used in the organic optoelectric device, enhancing charge mobility and stability, and included in layers such as the light emitting layer and electron transport layer to improve device performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic materials are used in organic optoelectric devices, then device structure and operation are maintained, but hole and electron mobility are insufficient and electrochemical stability is poor, limiting efficiency and lifespan

Engineering Contradiction:
Improveelectrochemical stabilityVSAvoidcharge mobility
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent employs composite organic materials comprising specific molecular structures with electron-transporting moieties (triazine, pyrimidine, pyridine rings) combined with hole-transporting moieties (carbazole, triphenylamine, diphenyl oxide groups). This composite molecular design enables simultaneous achievement of high hole and electron mobility while maintaining electrochemical stability, resolving the contradiction between reliability and productivity in organic optoelectric devices.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces different functional groups at specific positions within the molecular structure to create local functional zones. Electron-transporting groups are positioned at certain locations while hole-transporting groups are placed at other positions, allowing each region of the molecule to perform its specialized function. This local quality differentiation enables the material to achieve both high charge mobility and electrochemical stability simultaneously.

Inventive Principle:
Principle #3Local quality

2Productivity

If organic materials with high charge mobility are used, then device efficiency improves, but electrochemical stability deteriorates, reducing device lifespan

Engineering Contradiction:
Improvecharge mobilityVSAvoidelectrochemical stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent uses composite molecular structures that integrate both electron-transporting and hole-transporting functional groups within the same molecule. This composite design ensures that high charge mobility is achieved through the synergistic effect of both transport mechanisms, while electrochemical stability is maintained through the inherent stability of the aromatic ring systems and their specific arrangements.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes molecular parameters such as the size and position of aromatic rings, the number and type of substituent groups, and the overall molecular geometry to achieve the desired balance between charge mobility and electrochemical stability. By carefully adjusting these parameters, the material exhibits enhanced charge transport properties while maintaining long-term operational stability.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional organic layer materials are used, then basic device function is achieved, but efficiency and lifespan are limited due to insufficient charge transport and stability characteristics

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent employs composite organic materials with dual functionality (electron and hole transport) that simultaneously improve device efficiency through enhanced charge mobility and extend device lifespan through superior electrochemical stability. The specific molecular architecture with stabilized aromatic cores and strategically positioned functional groups ensures both high performance and long operational life.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces functionally differentiated regions within the organic layer materials, where electron-transporting moieties and hole-transporting moieties are spatially separated yet cooperatively arranged. This local quality differentiation optimizes charge transport pathways for high efficiency while the stable molecular backbone provides long-term durability, achieving both high device efficiency and extended lifespan.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound achieves high efficiency and extended lifespan by maintaining charge mobility and reducing crystallinity, leading to improved processibility and electrical characteristics in organic optoelectric devices.

Implementation Method 1

a hole-transporting compound or an electron-transporting compound, wherein the compound is represented by Formula (I)

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP3312255B1Compound for organic optoelectric device, organic optoelectric device and display device
Publication Date: 2022.04.06 SAMSUNG SDI CO LTD
  • EP3312255B1 patent drawingFigure 1~2
  • EP3312255B1 patent drawing
  • EP3312255B1 patent drawing

AI summary

The present invention relates to a compound for an organic optoelectric device, an organic optoelectric device, to which the compound is applied, and a display device, wherein the compound is represented by chemical formula 1. The detailed contents regarding chemical formula 1 are the same as defined in the specification.