Triblock Copolymer Ink for 3D Printed RF Devices

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Solution Overview

Problem

Current methods for fabricating low-loss dielectric materials for high-frequency radio devices, such as those operating in the Ka band, face challenges in precision and cost, particularly with polymeric and ceramic materials, as traditional techniques like casting, injection molding, and machining are either costly or laborious and limited in design flexibility.

Innovation Solution

A solvent-based 3D printing ink formulation using a triblock copolymer with aromatic or acrylate end blocks and aliphatic midblocks, exhibiting shear thinning properties, is developed for extrusion-based 3D printing, allowing for the creation of low-loss dielectric structures with controlled dielectric properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional casting or injection molding is used to fabricate low-loss dielectric structures, then manufacturing precision can be achieved, but device complexity and cost increase significantly

Engineering Contradiction:
Improvefabrication precisionVSAvoidmanufacturing complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent changes the rheological parameters of the ink formulation by incorporating shear-thinning polymers and adjusting viscosity to enable direct 3D printing. This allows the material to flow easily during extrusion then maintain shape after deposition, achieving manufacturing precision through material property modification rather than complex tooling

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces traditional mechanical manufacturing methods (casting, injection molding, machining) with a digital 3D printing process. The deposition system uses computer-controlled extrusion to build structures layer by layer, substituting complex mechanical tooling and multiple fabrication steps with a single digital manufacturing process

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Adaptability or versatility

If traditional machining is used to create customized high-frequency device designs, then design flexibility is achieved, but labor intensity and time consumption increase

Engineering Contradiction:
Improvedesign flexibilityVSAvoidfabrication time
Core Design Contradiction:
Adaptability or versatilityVSLoss of time

Solution Approach 1:

The patent performs preliminary digital modeling and path planning before physical fabrication. The 3D printing process uses pre-programmed deposition paths to automatically create customized geometries, eliminating the need for time-consuming manual measurements, tool setup, and iterative adjustments required in traditional machining

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent employs dynamic ink formulations with shear-thinning properties that adapt their viscosity during the printing process. The material becomes less viscous under shear stress during extrusion for smooth flow, then rapidly recovers viscosity after deposition to maintain precise geometric features, enabling complex customized designs to be fabricated quickly without manual intervention

Inventive Principle:
Principle #15Dynamics

3Reliability

If high-frequency dielectric materials are fabricated using conventional methods, then material performance can be maintained, but material selection is limited

Engineering Contradiction:
Improvedielectric performanceVSAvoidmaterials selection
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent uses composite ink formulations combining polymer matrices with dielectric fillers or functional additives. This allows tailoring of dielectric properties (permittivity, loss tangent) while maintaining processability through 3D printing. The composite approach enables selection from a wide range of materials including polymers, ceramics, and their composites, expanding material selection beyond what is available through traditional single-material casting or molding

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the fabrication of high-resolution, low-loss dielectric structures with improved precision and flexibility, reducing costs and complexity, while maintaining excellent dielectric performance across the Ka band.

Implementation Method 1

The ink formulation exhibits a shear thinning threshold of about 0.02 rad/sec or less

Methodology Applied
Scientific EffectShear thinning: Shear Thinning

Implementation Method 2

the ink formulation is treated to remove or cure the solvent, thereby forming a 3D printed RF device

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS10851251B2Block copolymer ink formulation for 3D printing and method of making a 3D printed radiofrequency (RF) device
Publication Date: 2020.12.01 MASSACHUSETTS INST OF TECH
  • US10851251B2 patent drawing
  • US10851251B2 patent drawing
  • US10851251B2 patent drawing

AI summary

An ink formulation for 3D printing comprises a triblock copolymer in a solvent, where the triblock copolymer includes end blocks comprising an aromatic or acrylate polymer and a midblock between the end blocks comprising an aliphatic polymer. The ink formulation exhibits a shear thinning threshold of about 0.02 rad/sec or less. A method of making a 3D printed radiofrequency (RF) device comprises extruding an ink formulation from a deposition nozzle moving relative to a substrate, where the ink formulation comprises a triblock copolymer in a solvent and the triblock copolymer includes end blocks comprising an aromatic or acrylate polymer and a midblock between the end blocks comprising an aliphatic polymer. One or more continuous filaments comprising the ink formulation are deposited in a predetermined pattern on the substrate, and the ink formulation is treated to remove or cure the solvent, thereby forming a printed RF device.