Triblock Copolymer Liquid Composition for Perfume Capsule Stability

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Solution Overview

Problem

Laundry compositions with perfume capsules face issues of perfume leakage and oxidation of ingredients, particularly in water-soluble unit-dose articles, which affect the availability and stability of perfumes and other components.

Innovation Solution

A liquid composition comprising ethylene oxide-propylene oxide triblock copolymers is used to reduce perfume leakage, along with specific non-aqueous solvents and alcohol alkoxylated nonionic surfactants to enhance stability and compatibility with water-soluble films.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If perfume capsules are used in laundry compositions, then fragrance delivery is improved, but perfume leakage from capsules occurs

Engineering Contradiction:
Improvefragrance deliveryVSAvoidcapsule integrity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent introduces a specific polymer electrolyte as an intermediary substance between the perfume capsule and the laundry composition. This polymer electrolyte acts as a mediator that prevents direct harmful interactions while maintaining fragrance delivery, thereby resolving the contradiction between effective fragrance release and capsule integrity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical environment by controlling pH levels and ionic strength through the polymer electrolyte. By changing these parameters, the capsule membrane stability is improved while still allowing controlled fragrance release, thus resolving the contradiction between capsule integrity and fragrance delivery.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If perfume capsules are used in water-soluble unit-dose articles, then convenience is improved, but perfume leakage increases

Engineering Contradiction:
Improveconvenience of useVSAvoidcapsule integrity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The polymer electrolyte serves as a protective intermediary in the water-soluble unit-dose article, creating a buffer zone that protects the perfume capsule from premature contact with water while maintaining the convenience of the water-soluble format.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies preliminary protection measures by incorporating the polymer electrolyte into the unit-dose article structure before use. This preliminary action creates a protective environment that prevents leakage during storage and transport while enabling convenient water-soluble dissolution during use.

Inventive Principle:
Principle #10Preliminary action

3Quantity of substance

If perfume ingredients are present in laundry composition, then fragrance is improved, but oxidation of other ingredients occurs

Engineering Contradiction:
Improvefragrance availabilityVSAvoidoxidation of ingredients
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The polymer electrolyte acts as a protective intermediary between the perfume ingredients and other laundry composition ingredients. It creates a chemical buffer that prevents oxidation reactions while allowing the fragrance to remain available, thus resolving the contradiction between fragrance availability and prevention of ingredient oxidation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a chemically inert microenvironment around the perfume ingredients through the polymer electrolyte system. This inert environment prevents oxidative reactions with other ingredients while maintaining fragrance availability, resolving the contradiction between fragrance presence and ingredient stability.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

4Adaptability or versatility

If water content in laundry composition is reduced for unit-dose articles, then compatibility with water-soluble film is improved, but perfume stability is affected

Engineering Contradiction:
Improvecompatibility with water-soluble filmVSAvoidperfume stability
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical parameters by introducing polymer electrolytes that can maintain perfume stability in low-water environments. This parameter change allows the composition to be compatible with water-soluble films while preserving perfume integrity during storage and dissolution.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively minimizes perfume leakage and maintains the integrity of perfume and other ingredients, ensuring consistent fragrance delivery and product stability in water-soluble unit-dose articles.

Implementation Method 1

comprising from 5 to 90%, preferably from 30% to 90%, more preferably from 40% to 90% by weight of the composition of an ethylene oxide - propylene oxide triblock copolymer

Methodology Applied
Scientific EffectAmphiphilic copolymer interface formation: Amphiphiles

Implementation Method 2

Another negative effect can be that the perfume ingredients, can oxidize other ingredients of the laundry composition

Methodology Applied
Scientific EffectOxidation prevention: Oxidation

Implementation Method 3

comprising from 1 to 20%, preferably from 3 to 10%, more preferably from 3 to 5% by weight of the composition of alcohol alkoxylated nonionic surfactant

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentEP4640808A1Liquid composition with perfume capsules
Publication Date: 2025.10.29 PROCTER & GAMBLE CO
  • EP4640808A1 patent drawing
  • EP4640808A1 patent drawing
  • EP4640808A1 patent drawing

AI summary

A liquid composition comprising: i) from 5 to 90% by weight of the composition of an ethylene oxide - propylene oxide triblock copolymer having one of the following structures: a) an ethylene oxide-propylene oxide-ethylene oxide (EO/PO/EO) triblock copolymer, wherein the copolymer comprises a first EO block, a second EO block and PO block and wherein the first EO block and the second EO block are linked to the PO block; b) a propylene oxide-ethylene oxide-propylene oxide (PO/EO/PO) triblock copolymer, wherein the copolymer comprises a first PO block, a second PO block and EO block and wherein the first PO block and the second PO block are linked to the EO block; ii) from 1 to 50% by weight of the composition of perfume capsules; iii) less than 25% by weight of the composition of water; and iv) preferably less than 5% by weight of the composition of anionic surfactant.