Triboelectric Generator Using Self-Poled Nylon-11 Nanowires

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Solution Overview

Problem

Current triboelectric nanogenerators (TENGs) face limitations in mechanical energy harvesting due to the focus on tribo-negative materials, with tribo-positive materials like Nylon-11 requiring harsh processing conditions for optimal performance, such as extreme crystallization and electrical poling, which are inefficient and difficult to achieve.

Innovation Solution

A novel gas-flow assisted nano-template (GANT) infiltration method is developed to fabricate self-poled δ'-phase Nylon-11 nanowires within anodized aluminum oxide (AAO) templates, achieving enhanced surface charge density and crystallinity without the need for subsequent stretching and poling, thereby improving TENG performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If Nylon-11 is used as a tribo-positive material requiring extreme crystallization and electrical poling, then the TENG performance is improved, but the processing complexity and difficulty increase significantly

Engineering Contradiction:
ImproveTENG performanceVSAvoidprocessing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by pre-forming the Nylon-11 material with the desired crystalline structure and polarized state before incorporating it into the TENG device. The gas-flow assisted nano-template method creates self-poled nanowires during the fabrication process itself, eliminating the need for subsequent poling operations. This preliminary structuring of the material resolves the contradiction by achieving high performance through simplified processing.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces the traditional mechanical stretching and electrical poling processes with a gas-flow assisted infiltration method. Instead of applying mechanical stress and high voltage fields to achieve the desired material structure, the invention uses controlled gas flow through nano-templates to deposit and structure the Nylon-11 material in its final functional state during fabrication, thereby eliminating complex post-processing steps.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Quantity of substance

If conventional stretching and poling processes are used to achieve optimal Nylon-11 performance, then the surface charge density increases, but the manufacturing time and process steps increase

Engineering Contradiction:
Improvesurface charge densityVSAvoidmanufacturing time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The patent merges multiple process steps into a single integrated operation. The gas-flow assisted nano-template method combines material deposition, crystallization, and polarization induction into one simultaneous process. As the gas flows through the nano-template and deposits Nylon-11, the material self-organizes into the desired crystalline structure and polarized state in real-time, achieving high surface charge density without sequential processing steps, thereby reducing manufacturing time.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent applies self-service by enabling the Nylon-11 material to self-organize and self-pole during the deposition process. The gas-flow assisted infiltration causes the material to automatically form the desired crystalline structure and charge distribution through the constraints and fields present during fabrication, without requiring external stretching or poling interventions. This self-structuring capability eliminates time-consuming post-processing operations.

Inventive Principle:
Principle #25Self-service

3Manufacturing precision

If extreme processing conditions are applied to Nylon-11, then the crystallinity and surface charge density improve, but the ease of manufacture decreases

Engineering Contradiction:
ImprovecrystallinityVSAvoidease of processing
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent changes the processing parameters from extreme conditions to controlled, moderate conditions. Instead of applying high stress, high voltage, or extreme temperatures to achieve crystallinity and polarization, the gas-flow assisted nano-template method uses controlled gas flow rates, temperature gradients, and pressure differentials during deposition. These modified parameters achieve the same or better material structure under more manageable and scalable manufacturing conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a gas flow as an intermediary medium to achieve the desired material structure. The gas serves as a carrier that delivers the Nylon-11 precursor through the nano-template while simultaneously providing the thermal and mechanical conditions needed for crystallization and polarization. This intermediary approach replaces direct application of extreme conditions with a more controlled indirect process, improving ease of manufacture while maintaining high crystallinity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a ten-fold increase in output power density compared to conventional aluminum-based TENGs, demonstrating improved mechanical energy harvesting capabilities and reliability under various conditions.

Implementation Method 1

A novel gas-flow assisted nano-template (GANT) infiltration method is developed to fabricate self-poled δ'-phase Nylon-11 nanowires within anodized aluminum oxide (AAO) templates

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

A novel gas-flow assisted nano-template (GANT) infiltration method is developed to fabricate self-poled δ'-phase Nylon-11 nanowires within anodized aluminum oxide (AAO) templates

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

A more recent approach has been through the use of triboelectric generators based on contact electrification and electrostatic induction between materials having dissimilar electron affinities

Methodology Applied
Scientific EffectContact electrification: Triboelectric Effect

Implementation Method 4

A more recent approach has been through the use of triboelectric generators based on contact electrification and electrostatic induction between materials having dissimilar electron affinities

Methodology Applied
Scientific EffectElectrostatic induction: Electrostatic Induction

Data Source

PatentEP3659249B1Triboelectric generator, method for manufacture thereof and elements thereof
Publication Date: 2021.08.11 CAMBRIDGE ENTERPRISE LTD
  • EP3659249B1 patent drawingFigure 1
  • EP3659249B1 patent drawingFigure 2
  • EP3659249B1 patent drawingFigure 3

AI summary

A triboelectric generator has a first generator element and a second generator element. The first and second generator elements are arranged so that relative movement between them generates a potential difference between them due to a triboelectrification effect. The first generator element comprises a first triboelectric material having a first electron affinity. The second generator element comprises a second triboelectric material having a second electron affinity, different to the first electron affinity. The first generator element comprises a template structure having an array of channels extending in the template structure, the channels being substantially filled with the first material to define a templated array of nanowires of the first material. The nanowires can be formed of a polymeric material such as Nylon (11), or another polar polymer material.