Tridentate Organometallic Compounds for Brighter, Lower-Voltage OLEDs

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Solution Overview

Problem

Existing organic light-emitting devices face challenges in achieving optimal performance in terms of brightness, driving voltage, and response speed, particularly in the design and composition of the emission layer and electron transport region.

Innovation Solution

The introduction of an organometallic compound represented by Formula 1, comprising specific metal elements and tridentate ligands, which can be incorporated into the emission layer to enhance the recombination of holes and electrons, thereby improving the efficiency and performance of the organic light-emitting device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional emission layer materials are used, then device structure is simple, but brightness is insufficient and driving voltage is high

Engineering Contradiction:
ImprovebrightnessVSAvoiddriving voltage
Core Design Contradiction:
Illumination intensityVSPower

Solution Approach 1:

The patent employs composite materials by combining a metal center (M) with specific tridentate ligands (LA and LB) to create an organometallic compound. This composite structure enables enhanced electron transport and recombination properties, resulting in improved brightness and reduced driving voltage compared to conventional single-material emission layers.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes parameter changes by systematically varying the metal center (M) and ligand structures (LA and LB) to optimize the emission layer's electrical and optical properties. By adjusting these chemical parameters, the device achieves better brightness-voltage characteristics while maintaining structural integrity.

Inventive Principle:
Principle #35Parameter changes

2Speed

If conventional emission layer materials are used, then manufacturing process is simple, but response speed is slow

Engineering Contradiction:
Improveresponse speedVSAvoidmanufacturing process complexity
Core Design Contradiction:
SpeedVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by optimizing the organometallic compound's structure (metal center and ligand configuration) to enhance carrier recombination kinetics. This improves response speed while the compounds remain synthesizable through conventional organic chemistry methods, maintaining ease of manufacture.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional emission layer materials are used, then device structure is simple, but efficiency is low

Engineering Contradiction:
ImproveefficiencyVSAvoidemission layer composition
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent uses composite materials in the form of defined organometallic compounds with specific metal centers and tridentate ligands. This composite approach enhances carrier recombination efficiency and exciton utilization, improving device efficiency. The structured composition (Formula 1) provides clarity that simplifies the manufacturing process despite the enhanced functionality.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the organometallic compound enhances the brightness and reduces the driving voltage, leading to improved response speed and overall performance of the organic light-emitting device.

Implementation Method 1

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transit (e.g., transition or relax) from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12398163B2Organometallic compound and organic light-emitting device including the same
Publication Date: 2025.08.26 SAMSUNG DISPLAY CO LTD
  • US12398163B2 patent drawing
  • US12398163B2 patent drawing
  • US12398163B2 patent drawing

AI summary

An organometallic compound is represented by Formula 1. An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; an organic layer between the first electrode and the second electrode and including an emission layer; and at least one of the organometallic compound represented by Formula 1.