Non-Aqueous Triketone Herbicide Formulation for Dilution Stability

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Solution Overview

Problem

Existing herbicide formulations, particularly those containing Triketone compounds, face challenges in achieving chemical and dispersion stability, especially when diluted with water, and often rely on environmentally harmful solvents, necessitating the development of stable and efficient non-aqueous formulations that maintain stability and efficiency.

Innovation Solution

A stable non-aqueous agrochemical formulation comprising a Triketone herbicide, additional herbicides, vegetable oils, and a surfactant system with ionic phosphated Tristyrylphenol alkoxylate and non-ionic Tristyrylphenol alkoxylate, enhancing chemical and dispersion stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If regular organic solvents are used in herbicide formulations, then chemical stability of the herbicide is improved, but environmental pollution and flammability increase

Engineering Contradiction:
Improvechemical stabilityVSAvoidenvironmental pollution
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the fundamental parameter of the solvent system from conventional organic solvents to vegetable oil-based solvents. This parameter change maintains the chemical stability required for herbicide formulation while eliminating the harmful environmental effects and flammability associated with traditional organic solvents. The vegetable oil base provides a stable, non-flammable, and environmentally benign alternative.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs vegetable oils as a renewable, biodegradable solvent system that can be readily degraded in the environment. This replaces persistent organic solvents with a natural, short-lived carrier that breaks down harmlessly, reducing environmental accumulation and pollution while maintaining formulation stability during the product's service life.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If Triketone herbicides are formulated in aqueous systems, then environmental friendliness is improved, but chemical stability and dispersion stability deteriorate

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidchemical stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent introduces vegetable oil as an intermediary solvent system that bridges the gap between aqueous environmental friendliness and chemical stability requirements. The vegetable oil base acts as a mediator that provides the hydrophobic environment needed for Triketone stability while being inherently more environmentally benign than conventional organic solvents, thus resolving the contradiction between stability and environmental friendliness.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If Triketone herbicides are formulated in aqueous systems, then environmental friendliness is improved, but dispersion stability after dilution deteriorates

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoiddispersion stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the solvent parameter from water-based to vegetable oil-based, which fundamentally alters the dispersion characteristics. The vegetable oil matrix provides better compatibility with Triketone herbicides, maintaining uniform dispersion stability even after dilution with water in the field, while preserving the environmental advantages of a natural oil base rather than synthetic solvents.

Inventive Principle:
Principle #35Parameter changes

4Stability of the object's composition

If conventional surfactant systems are used, then formulation stability is improved, but environmental impact increases

Engineering Contradiction:
Improveformulation stabilityVSAvoidenvironmental impact
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent applies local quality by selecting specific biodegradable surfactants that are tailored for use in vegetable oil-based formulations. These surfactants provide the necessary stabilization and emulsification properties locally within the oil matrix, ensuring formulation stability while maintaining overall environmental compatibility through their biodegradable nature and lower toxicity profiles.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation provides improved chemical stability and dispersion stability, allowing effective weed control with reduced environmental impact.

Implementation Method 1

a surfactant system comprising a mixture comprising an ionic phosphated Tristyrylphenol alkoxylate and a non-ionic Tristyrylphenol alkoxylate

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

enhancing efficiency... by way of increasing chemical stability as well as dispersion stability

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 3

one or more vegetable oils or derivatives thereof... as solvents

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS20260047575A1Novel formulation systems of triketone herbicide
Publication Date: 2026.02.19 ADAMA AGAN LTD

AI summary

The present invention relates to stable and efficient non-aqueous agrochemical formulations comprising a Triketone herbicide, at least one additional herbicide; one or more vegetable oils or derivatives thereof, a surfactant system comprising a mixture comprising an ionic phosphated Tristyrylphenol alkoxylate and a non-ionic Tristyrylphenol alkoxylate; and also it relates to methods for controlling undesired plant species by applying the said environment-friendly formulation after dilution with water to the plant species.