Triphenylene Derivative Matrix Materials for OLED Efficiency

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Solution Overview

Problem

Current organic electroluminescent devices (OLEDs) face challenges in efficiency, operating voltage, and lifetime, particularly for phosphorescent OLEDs, where the materials used beyond triplet emitters, such as matrix and charge transport materials, need improvement to enhance overall device performance.

Innovation Solution

The development of specific triphenylene derivative compounds as matrix materials or hole transport materials in OLEDs, which exhibit improved efficiency, longer lifetime, and lower operating voltage when used in phosphorescent emitters, offering a broader material choice for OLED production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional matrix materials are used in phosphorescent OLEDs, then device structure is simple, but efficiency is low and lifetime is short

Engineering Contradiction:
ImproveefficiencyVSAvoidmaterial structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure parameters of triphenylene derivatives by introducing specific substituents (diarylamine groups, carbazole groups, dibenzofuran groups) at defined positions (2,7-positions or 3,6-positions) to optimize electronic properties, HOMO/LUMO energy levels, and charge transport characteristics, thereby improving efficiency and lifetime without excessive complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite material systems by combining triphenylene derivative matrix materials with phosphorescent emitters and charge transport materials to form multi-component OLED structures that synergistically improve efficiency, voltage characteristics, and device lifetime

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If conventional materials are used in OLEDs, then manufacturing is simple, but operating voltage is high and lifetime is limited

Engineering Contradiction:
Improvedevice lifetimeVSAvoidoperating voltage
Core Design Contradiction:
Duration of action of stationary objectVSUse of energy by stationary object

Solution Approach 1:

The patent optimizes the HOMO and LUMO energy level parameters of triphenylene derivatives through systematic molecular design, adjusting substituent types and positions to achieve better energy level alignment with charge transport materials, reducing operating voltage and improving electron-hole balance for enhanced device lifetime

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops organic triphenylene derivative materials as alternatives to expensive and less stable inorganic materials, providing cost-effective organic-based solutions with improved stability and lifetime characteristics for OLED applications

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If phosphorescent emitters are used in OLEDs, then light emission is achieved, but efficiency and lifetime need improvement through material optimization

Engineering Contradiction:
Improvedevice efficiencyVSAvoidmaterial composition complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent introduces specific functional groups (diarylamine, carbazole, dibenzofuran) at specific positions (2,7- or 3,6-positions) of the triphenylene core to locally optimize electron transport, hole transport, and triplet energy levels, achieving improved efficiency without requiring complete structural redesign

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent designs triphenylene derivatives that simultaneously serve multiple functions: as matrix material, charge transport material, and triplet energy management component in phosphorescent OLEDs, reducing the need for separate specialized materials and simplifying overall device structure

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentUS20230295104A1Materials for organic electroluminescent devices
Publication Date: 2023.09.21 MERCK PATENT GMBH
  • US20230295104A1 patent drawing
  • US20230295104A1 patent drawing
  • US20230295104A1 patent drawing

AI summary

The present invention relates to compounds suitable for use in electronic devices, and to electronic devices, especially organic electroluminescent devices, comprising these compounds.