Triple Crosslinked Hydrogel for High-Temperature Cooling

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Solution Overview

Problem

Existing hydrogels lack high tensile strength, compression, and durability, with limited cooling periods, making them unsuitable for prolonged use in high-temperature environments.

Innovation Solution

A triple crosslinked cooling hydrogel composition comprising polyvinyl alcohol (PVA), polydimethylsiloxane (PDMS), and phase change materials (PCMs) with specific ratios, along with a crosslinking agent like glutaraldehyde, to create a robust and durable network that maintains cooling efficacy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional hydrogel compositions are used, then the material is simple to manufacture, but the tensile strength and compression resistance are insufficient

Engineering Contradiction:
Improvetensile strengthVSAvoidnetwork structure complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent employs a triple network composite structure combining PVA, PDMS, and PCM materials with different crosslinking mechanisms (chemical, physical, and phase-change crosslinks) to achieve high tensile strength and compression resistance while maintaining manufacturability through a systematic multi-step process

Inventive Principle:
Principle #40Composite materials

2Strength

If conventional hydrogel compositions are used, then the material is simple to manufacture, but the compression resistance and durability are insufficient

Engineering Contradiction:
Improvecompression resistanceVSAvoidnetwork structure complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The triple network composite incorporating PDMS provides exceptional compression resistance through its elastic recovery properties, while the integrated crosslinking system ensures durability under repeated compression cycles in harsh environments

Inventive Principle:
Principle #40Composite materials

3Duration of action of moving object

If conventional hydrogel compositions are used, then the cooling period is limited, but the composition complexity is low

Engineering Contradiction:
Improvecooling periodVSAvoidcomposition complexity
Core Design Contradiction:
Duration of action of moving objectVSDevice complexity

Solution Approach 1:

The patent incorporates phase change materials (PCMs) that undergo phase transitions at specific temperatures, absorbing and releasing latent heat to extend the cooling period significantly compared to conventional hydrogels, with the triple network structure maintaining structural integrity during these phase changes

Inventive Principle:
Principle #36Phase transitions

4Reliability

If the hydrogel is designed for high tensile strength and extended cooling period, then the durability in harsh conditions improves, but the manufacturing complexity increases

Engineering Contradiction:
Improvedurability in harsh conditionsVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The manufacturing process is segmented into distinct sequential steps (PVA network formation, PDMS incorporation, PCM integration, and crosslinking), allowing each component to be optimized independently while maintaining overall process feasibility and durability performance

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The triple crosslinked hydrogel exhibits enhanced tensile strength, compression, and extended cooling periods, making it suitable for repeated use in harsh conditions, such as high solar radiation and temperature environments.

Implementation Method 1

Phase change materials (PCMs), as an energy storage technology, can store large amounts of energy in the form of latent heat during the phase change process

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

Phase change materials (PCMs), as an energy storage technology, can store large amounts of energy in the form of latent heat during the phase change process

Methodology Applied
Scientific EffectLatent heat: Latent Heat

Implementation Method 3

A triple crosslinked cooling hydrogel composition comprising polyvinyl alcohol (PVA), polydimethylsiloxane (PDMS), and phase change materials (PCMs) with specific ratios, along with a crosslinking agent like glutaraldehyde, to create a robust and durable network

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentUS20240043729A1Type of triple network cooling hydrogel with high compressive and elastic
Publication Date: 2024.02.08 HONEYWELL SAFETY PRODUCTS USA INC
  • US20240043729A1 patent drawing
  • US20240043729A1 patent drawing
  • US20240043729A1 patent drawing

AI summary

The invention provides triple crosslinked cooling hydrogel compositions of high tensile strength, high compressibility, high elasticity, and long cooling period and methods of making the compositions. The compositions are useful in clothing and equipment for wear in high solar radiation environments and high temperature environments.