Truxene Derivative Layer Uniformity in OLED Devices

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Solution Overview

Problem

Truxene derivatives exhibit insufficient layer forming properties during coating methods, leading to uneven layer thickness and performance limitations such as short circuiting and uneven light emission in organic electroluminescent devices due to non-uniform electric fields.

Innovation Solution

A truxene derivative represented by Formula 1, with specific substituents and structures that enhance layer forming properties, including an amorphous structure and electron donating functions, is used in the emission, hole transport, and hole injection layers to improve uniformity and adhesion, reducing convex-concavo shapes and enhancing charge balance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional coating methods are used with traditional truxene derivatives, then the manufacturing process is simple, but the layer forming properties are insufficient leading to uneven layer thickness

Engineering Contradiction:
Improvelayer thickness uniformityVSAvoidlayer formation process complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent modifies the chemical structure parameters of the truxene derivative by introducing specific substituents (dibenzofuranyl, dibenzothienyl, carbazolyl, or fluorenyl groups at positions 2, 7, and 12) to change the molecular properties. This structural parameter change improves layer forming properties during coating, enabling uniform layer thickness without complicating the manufacturing process

Inventive Principle:
Principle #35Parameter changes

2Shape

If truxene derivatives with insufficient layer forming properties are used, then the device structure is simple, but convex-concavo shapes are generated on the layer surface

Engineering Contradiction:
Improvelayer surface uniformityVSAvoidmolecular structure complexity
Core Design Contradiction:
ShapeVSDevice complexity

Solution Approach 1:

The patent introduces specific functional groups (dibenzofuranyl, dibenzothienyl, carbazolyl, or fluorenyl) at specific positions (2, 7, and 12) of the truxene core structure. This local modification of molecular quality creates specific intermolecular interactions that promote uniform layer formation and prevent convex-concavo surface defects

Inventive Principle:
Principle #3Local quality

3Reliability

If uneven layer thickness is formed, then the manufacturing process is simple, but short circuiting and uneven light emission occur

Engineering Contradiction:
Improvedevice performance stabilityVSAvoidcoating process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

By changing the chemical structure parameters of the truxene derivative to include specific electron-donating groups at defined positions, the patent improves the material's inherent layer forming capability. This enables the formation of uniform, defect-free layers through simple coating processes, eliminating short circuiting and ensuring uniform light emission

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS10777751B2Truxene derivative and organic electroluminescence device including the same
Publication Date: 2020.09.15 SAMSUNG DISPLAY CO LTD
  • US10777751B2 patent drawing
  • US10777751B2 patent drawing
  • US10777751B2 patent drawing

AI summary

A truxene derivative having good layer forming properties during layer formation and an organic electroluminescent device including the same. The truxene derivative may be represented by Formula 1:A layer including the truxene derivative in the organic electroluminescent device may have a decreased number or concentration of convex-concavo () shapes, and performance limitations caused by non-uniformity in each layer of the organic electroluminescent device (for example, short circuiting or uneven light emission due to non-uniformity in an applied electric field) may be thereby prevented or reduced.