TSV Via Cleaning with Heated Atomized Inert-Gas Spray

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Solution Overview

Problem

Conventional semiconductor cleaning methods struggle to effectively clean high-aspect-ratio TSV vias due to difficulties in liquid infiltration and residue removal, especially when the hole diameter is small, leading to incomplete filling and defects.

Innovation Solution

A method involving a cleaning liquid and inert gas mixture is heated and atomized using an atomizer, with adjustable flow rates and pulse mode delivery, to efficiently wet and clean the inner walls and bottoms of TSV vias, followed by passivation and rinsing with atomized solutions to form a silicon oxide layer and remove residues.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional cleaning methods (slot ultrasonic cleaning, monolithic megasonic cleaning, monolithic high-pressure water jet cleaning) are used, then the cleaning process can be performed on wafer surfaces, but the cleaning liquid cannot effectively infiltrate high-aspect-ratio TSV vias due to surface tension, resulting in incomplete residue removal

Engineering Contradiction:
Improvecleaning quality of TSV viasVSAvoidsurface tension of cleaning liquid
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the physical state of the cleaning liquid from bulk liquid to aerosol by controlling parameters such as liquid particle size (1-10 μm), gas-to-liquid ratio, and injection pressure. This parameter transformation enables the cleaning liquid to overcome surface tension effects and effectively infiltrate high-aspect-ratio TSV vias, resolving the contradiction between cleaning quality and surface tension barriers

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The cleaning liquid undergoes a phase transition from liquid to aerosol (liquid-gas mixture) through atomization. This phase change reduces the effective surface tension impact on the cleaning liquid, allowing it to penetrate deep into narrow TSV vias while maintaining cleaning effectiveness, thus solving the infiltration problem caused by surface tension

Inventive Principle:
Principle #36Phase transitions

2Productivity

If the hole diameter of TSV blind hole is small and aspect ratio is large, then the TSV via density and integration level are improved, but the liquid exchange in the TSV blind hole becomes difficult due to surface tension

Engineering Contradiction:
ImproveTSV via densityVSAvoidliquid exchange in TSV blind hole
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent uses pneumatic atomization where compressed gas (pneumatic force) breaks up the cleaning liquid into fine aerosol particles. This pneumatic approach enables the cleaning liquid to be delivered into small-diameter, high-aspect-ratio TSV vias where conventional liquid delivery fails, thus maintaining ease of operation while achieving high TSV via density

Inventive Principle:
Principle #29Pneumatics and hydraulics

Solution Approach 2:

The patent transforms the cleaning liquid delivery from a bulk liquid phase to an aerosol phase, effectively adding a gaseous dimension to the liquid. This dimensional change allows the cleaning medium to access narrow TSV vias that would be inaccessible to conventional liquid cleaning, enabling both high via density and effective liquid exchange

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Productivity

If conventional cleaning methods are used, then the equipment structure is relatively simple, but the cleaning efficiency and residue removal capability are insufficient for high-aspect-ratio TSV vias

Engineering Contradiction:
Improvecleaning efficiencyVSAvoidcleaning equipment structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent introduces an intermediary aerosolization system that converts cleaning liquid into fine particles using compressed gas. This intermediary mechanism bridges the gap between conventional simple equipment and the need for high cleaning efficiency in complex high-aspect-ratio TSV vias, achieving improved productivity with moderate equipment complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enhances cleaning efficiency by ensuring thorough wetting and removal of residues within TSV vias, improving the quality of TSV via cleaning and passivation, and reducing the thickness of surface adsorption layers, thus addressing the limitations of conventional methods.

Implementation Method 1

atomizing the cleaning liquid in an atomizer, to spray on a wafer surface and to wet an inner wall and a bottom of the through via

Methodology Applied
Scientific EffectAtomization:

Implementation Method 2

the liquid in the through via is difficult to infiltrate due to the surface tension of the cleaning liquid

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 3

heating a cleaning liquid to a predetermined temperature

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

mixing the cleaning liquid with an inert gas and entering into a cleaning chamber

Methodology Applied
Scientific EffectGas flow:

Data Source

PatentUS11854794B2Semiconductor cleaning equipment and method for cleaning through vias using the same
Publication Date: 2023.12.26 NAT CENT FOR ADVANCED PACKAGING CO LTD
  • US11854794B2 patent drawing
  • US11854794B2 patent drawing
  • US11854794B2 patent drawing

AI summary

A method for cleaning a through via including the following steps is provided: heating a cleaning fluid to a predetermined temperature; mixing the cleaning liquid with an inert gas and entering into a cleaning cavity; atomizing the cleaning liquid in an atomizer to spray on a wafer surface and to wet an inner wall and a bottom of the through via; and closing a cleaning liquid valve.