Tubular Spectroscopy Cell with Parallel Tubes for Benzene Detection

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Solution Overview

Problem

Existing spectroscopy devices for analyzing chemically contaminated carbon dioxide face challenges in achieving high reproducibility, low cost, and simple applicability while maintaining measurement accuracy, especially in detecting small amounts of benzene and methane, due to environmental influences and high noise levels.

Innovation Solution

A spectroscopy device with a stabilized tubular measuring cell, where the measuring cell is rigidly connected to parallel tubes made of materials with a similar thermal expansion coefficient to glass, reducing vibration-induced noise and increasing absorption coefficients, combined with a compact design and thermoregulation for accurate benzene detection, using a xenon light source and high-resolution detectors for enhanced signal processing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If highly sensitive measuring instruments are used to detect minute quantities of gas with required accuracy, then measurement precision is improved, but device complexity and cost increase

Engineering Contradiction:
Improvedetection accuracy of benzene at 3 ppbVSAvoidcomplexity of measuring device setup
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The measuring device is segmented into a compact integrated unit combining the light source, measuring cell, and detector in a single housing. This modular segmentation allows high-precision measurement capabilities while reducing overall system complexity and facilitating easier deployment compared to distributed complex instrument setups.

Inventive Principle:
Principle #1Segmentation

2Measurement precision

If a sufficiently long transmission path is used to achieve signal strength above noise threshold, then measurement precision is improved, but device complexity increases

Engineering Contradiction:
Improvesignal strength above noise thresholdVSAvoidcomplexity of optical assembly
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The optical components are nested within the tubular measuring cell structure, with the light source, mirrors, and detector arranged concentrically along the transmission path. This nesting approach achieves a long effective transmission path (2 meters) within a compact form factor, maintaining high measurement precision while minimizing device complexity and spatial requirements.

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The optical path is folded back on itself using mirrors arranged at 45-degree angles, transforming a linear transmission path into a multi-dimensional zigzag configuration within the tube. This allows achieving a 2-meter optical path length within a compact 10 cm x 10 cm x 30 cm housing, resolving the contradiction between long transmission path and simple device structure.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Measurement precision

If rigid connections are used to stabilize the measuring cell against environmental influences, then measurement precision is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improvereproducibility of measurement resultsVSAvoidprecision of rigid connections
Core Design Contradiction:
Measurement precisionVSManufacturing precision

Solution Approach 1:

The connecting elements are designed with adjustable positioning mechanisms that allow fine-tuning of the optical alignment after assembly. This parameter adjustment capability compensates for manufacturing tolerances in the rigid connections, ensuring stable mechanical coupling and consistent optical alignment without requiring extremely tight manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides high reproducibility and accuracy in detecting benzene at low concentrations with reduced noise and cost-effective production, enabling reliable monitoring of chemically contaminated carbon dioxide, even in varying temperature conditions.

Implementation Method 1

The tube is rigidly connected to parallel tubes (3a, 3b) by means of connecting elements (4a, 4b), each fixed circumferentially and completely encompassing the circumference of the tube, for stabilizing the measuring cell against environmental influences

Methodology Applied
Scientific EffectVibration: Vibration

Implementation Method 2

the tubes arranged parallel to the measuring cell's direction of extension are made of a material with a coefficient of thermal expansion equal to or smaller than that of glass

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 3

Absorption spectroscopy is an important tool for trace analysis, i.e., the determination of minute quantities of a substance alongside larger quantities of its main components

Methodology Applied
Scientific EffectAbsorption spectroscopy: Absorption Spectroscopy

Implementation Method 4

The fundamental principle of the present invention is therefore the damping of vibrations induced by environmental influences and their rapid decay due to the increased inertia of the resonating body

Methodology Applied
Scientific EffectDamping: Damping

Data Source

PatentEP1845362B1Spectroscopy apparatus
Publication Date: 2021.12.15 KRIEG GUNTHER PROF DR ING
  • EP1845362B1 patent drawingFigure 1

AI summary

The device (1) has a tubular measuring cell (2) with pipes (3a, 3b) that are arranged in parallel to extending direction of the measuring cell. The pipes have a rigid connection, and are formed of a material such as glass, having smaller or equal thermal expansion coefficient. A light source (6) e.g. deuterium lamp, radiates light within ultraviolet (UV) range, where uncoupled light radiation is fed into a detector/spectrometer (7). An independent claim is also included for a method for spectroscopy with a tubular measuring cell.