Mechanically Tunable Adhesive via Strain-Induced Surface Wrinkles

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Solution Overview

Problem

Current adhesives are designed for specific applications and have fixed adhesion properties, lacking the ability to form various wrinkle patterns with tunable adhesive force, which is essential for advanced technologies like stretchable electronics and robotics.

Innovation Solution

Mechanically applying strain to a substrate, coating it with a layer having a higher Young's Modulus, and releasing the strain to create predetermined rippled surface structures, allowing for adjustable adhesion by controlling the amount and direction of strain applied.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If adhesive materials are designed for specific applications with fixed adhesion properties, then the adhesion performance is optimized for that application, but the adaptability to different applications is reduced

Engineering Contradiction:
Improveadhesion performanceVSAvoidadaptability to different applications
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent applies the dynamics principle by creating an adhesive system where the surface topology can be dynamically changed through mechanical strain. The wrinkle patterns on the adhesive surface can be transformed from a flat state to a rippled state by applying strain, allowing the same adhesive material to adapt its adhesion properties for different applications. This dynamic transformation enables the adhesive to switch between high adhesion (flat state) and low adhesion (rippled state) as needed.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent applies parameter changes by modifying the physical state of the adhesive surface through mechanical strain. By changing the strain level applied to the adhesive, the surface morphology parameters (wrinkle amplitude, wavelength, and coverage) are altered, which directly changes the adhesion properties. This allows continuous tuning of adhesion strength without changing the material composition.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If wrinkle patterns are formed on adhesive surfaces, then adhesion control is enabled, but the complexity of the surface structure increases

Engineering Contradiction:
Improveadhesion controlVSAvoidsurface structure complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent applies the self-service principle by utilizing the adhesive material's own mechanical properties to generate the wrinkle patterns. The wrinkles are formed through internal buckling forces that arise when a thin rigid coating is applied over a pre-strained soft substrate. The system uses its own elastic energy storage and release to create the surface topology without requiring external tools or complex fabrication processes.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces complex mechanical surface patterning systems with a simpler chemical-coating approach. Instead of using mechanical tools to create wrinkles, the invention uses a thin coating layer (such as metal or oxide) deposited on a pre-strained substrate. The wrinkle formation is achieved through the mechanical relaxation of the pre-strained state combined with the coating application, substituting complex mechanical patterning with a more straightforward coating process.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Shape

If a thin rigid coating is applied on a pre-strained soft substrate, then wrinkle formation is achieved through internal buckling, but the manufacturing precision requirement increases

Engineering Contradiction:
Improvewrinkle pattern formationVSAvoidstrain control precision
Core Design Contradiction:
ShapeVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by pre-straining the soft substrate before applying the thin rigid coating. This preliminary deformation stores elastic energy in the substrate that will be released during the coating application process. The pre-strain is applied to a specific level (e.g., 20-60%) before coating, and this predetermined state ensures that the subsequent coating formation produces the desired wrinkle patterns through controlled buckling when the pre-strain is released.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables reversible and real-time tunability of adhesion forces, offering a wider range of adhesion control without requiring specific surface chemistry, suitable for applications in micro- and nanoelectronics, biotechnology, and robotics.

Implementation Method 1

One widely adopted simple and effective approach is based on internal buckling force equilibrium within materials by coating a hard thin layer (through metal deposition or surface oxidization) on top of a pre-strained bulk substrate (i.e., heated), such as poly(dimethylsiloxane) (PDMS), followed by release of the pre-strain.

Methodology Applied
Scientific EffectInternal buckling:

Implementation Method 2

The ability to actively induce features and textures on surfaces has been of great interest for many potential applications... various methodologies have been investigated to spontaneously form self organized structures with controlled morphologies

Methodology Applied
Scientific EffectSelf-organization: Self-Assembly

Implementation Method 3

One method of oxidizing the surface is exposing the surface to ultraviolet light and oxygen (via oxygen plasma treatment, for example).

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 4

exposing the surface to ultraviolet light and oxygen (via oxygen plasma treatment, for example).

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 5

mechanically applying strain to a substrate, coating it with a layer having a higher Young's Modulus, and releasing the strain to create predetermined rippled surface structures

Methodology Applied
Scientific EffectElasticity: Elasticity

Data Source

PatentUS8372230B2Adhesives with mechanical tunable adhesion
Publication Date: 2013.02.12 THE TRUSTEES OF THE UNIV OF PENNSYLVANIA
  • US8372230B2 patent drawing
  • US8372230B2 patent drawing
  • US8372230B2 patent drawing

AI summary

The invention concerns a method for making an article having a tunable adhesive, said method comprising applying strain to mechanically deform a substrate in at least one direction; applying a rigid coating layer on the substrate; and releasing the strain to form an article having a rippled surface. Ripple characteristics can be altered by mechanical strain in real time which further changes the adhesion properties.