Tungsten Bronze Complex for Thermal Isolation

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Solution Overview

Problem

Current thermal isolation materials for windows and vehicles face challenges in achieving high visible light transmittance while maintaining high infrared radiation absorption efficiency, which is essential for energy savings and carbon reduction.

Innovation Solution

A tungsten bronze complex with a specific formula (M1xM2yWOz) is developed, comprising a mixture of cubic and hexagonal tungsten bronze, where M1 is Li or Na, and M2 is K, Rb, or Cs, which is fabricated through a method involving tungsten-containing precursors, alkali metal compounds, and thermal treatment to achieve the desired molar ratios and particle sizes, resulting in a material that effectively absorbs infrared radiation while allowing high visible light transmittance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If metal oxides are used in thermal isolation film, then infrared radiation absorption efficiency is improved, but visible light transmittance deteriorates

Engineering Contradiction:
Improveinfrared radiation absorption efficiencyVSAvoidvisible light transmittance
Core Design Contradiction:
Loss of energyVSIllumination intensity

Solution Approach 1:

The patent uses tungsten bronze complex as a composite material that combines multiple metal elements (M1 and M2) with tungsten in a specific ratio. This composite structure enables simultaneous achievement of high infrared absorption efficiency and high visible light transmittance, resolving the contradiction between energy loss reduction and illumination maintenance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the stoichiometric parameters of the tungsten bronze complex by controlling the ratios of M1, M2, and W atoms. By adjusting these compositional parameters within specific ranges, the material achieves optimal balance between infrared absorption and visible light transmission properties.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If thermal isolation film is formed on window glass, then energy savings are achieved, but manufacturing complexity increases

Engineering Contradiction:
Improveenergy savingsVSAvoidmanufacturing complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent controls the formation of cubic and hexagonal phases by adjusting thermal treatment parameters (temperature and time). This parameter optimization simplifies the manufacturing process by achieving desired material properties through controlled heating rather than complex multi-step synthesis procedures.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The tungsten bronze complex achieves over 65% average visible light transmittance and superior infrared radiation absorption efficiency, outperforming comparative examples by effectively balancing transmittance and absorption requirements.

Implementation Method 1

a thermal isolation material having a high visible light transmittance and a high infrared radiation absorption efficiency

Methodology Applied
Scientific EffectInfrared absorption: Absorption (EM radiation)

Implementation Method 2

high visible light transmittance

Methodology Applied
Scientific EffectLight transmission:

Implementation Method 3

subjecting the mixture to a thermal treatment, obtaining the aforementioned infrared absorption material. The thermal treatment includes a first heating step and a second heating step

Methodology Applied
Scientific EffectThermal treatment: Heating

Data Source

PatentUS9434652B2Infrared absorption material, method for fabricating the same, and thermal isolation structure employing the same
Publication Date: 2016.09.06 IND TECH RES INST
  • US9434652B2 patent drawing
  • US9434652B2 patent drawing
  • US9434652B2 patent drawing

AI summary

The disclosure provides an infrared absorption material, a method for fabricating the same, and a thermal isolation structure employing the same. The infrared absorption material includes a tungsten bronze complex having a formula of M1xM2yWOz, wherein 0.6≦x≦0.8, 0.2≦y≦0.33, 0.8≦x+y<1, and 2≦z≦3; M1 is Li, or Na; and, M2 is K, Rb, or Cs. In particular, the tungsten bronze complex consists of a cubic tungsten bronze (CTB) and a hexagonal tungsten bronze (HTB).