Tungsten Bronze Nanoparticle Face Shield for Electric Arc Protection

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Solution Overview

Problem

Electric arcs from high voltage equipment pose a significant risk to electrical workers, causing injuries and fatalities due to high temperatures, and existing personal protective equipment does not adequately address the need for effective electric-arc resistance in face shields.

Innovation Solution

A transparent plastic composition incorporating inorganic nanoparticles, specifically crystalline tungsten bronze nanoparticles dispersed in a transparent polymer substrate, provides electric-arc resistance while maintaining transparency and thermal stability, allowing for the development of IR-blocking face shields.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional face shield materials are used, then manufacturing is simple and cost-effective, but electric-arc resistance and thermal stability are insufficient

Engineering Contradiction:
Improveelectric-arc resistanceVSAvoidmaterial composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining a transparent polymer substrate with inorganic nanoparticles (tungsten oxide, tungsten bronze, or indium tin oxide). This composite structure provides both the transparency and formability of polymers and the electric-arc resistance and thermal stability of inorganic particles, resolving the contradiction between reliability and material complexity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physical parameters of the face shield material by incorporating nanoparticles at specific concentrations (0.1-5% by weight). This parameter modification enhances the material's thermal stability and electric-arc resistance without significantly altering its transparency or mechanical properties, allowing improved reliability with controlled complexity.

Inventive Principle:
Principle #35Parameter changes

2Temperature

If inorganic nanoparticles are incorporated to improve electric-arc resistance, then thermal stability and arc protection are enhanced, but manufacturing complexity increases

Engineering Contradiction:
Improvethermal stabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by pre-dispersing the inorganic nanoparticles in a liquid carrier or master batch before incorporating them into the polymer matrix. This pre-dispersion step ensures uniform distribution of nanoparticles, preventing agglomeration and simplifying the subsequent molding process, thereby enhancing thermal stability while managing manufacturing complexity.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses a liquid carrier or dispersion medium as an intermediary to facilitate the incorporation of hydrophobic inorganic nanoparticles into the polymer matrix. This intermediary enables uniform distribution and stable incorporation of particles during processing, making the manufacturing of thermally stable composite materials more manageable.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Illumination intensity

If conventional materials are used, then manufacturing is straightforward, but transparency and visibility are compromised when adding protective features

Engineering Contradiction:
ImprovetransparencyVSAvoidelectric-arc protection
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent applies local quality by using nanoparticles that provide electric-arc protection specifically in the UV and infrared regions while maintaining high visible light transmission. The nanoparticles are distributed throughout the material matrix, providing localized protection at the molecular level without affecting the macroscopic transparency needed for worker visibility.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes the optical properties of specific inorganic nanoparticles (particularly indium tin oxide and tungsten bronze) that exhibit selective absorption in the infrared spectrum while remaining transparent in the visible range. This allows the material to change its optical properties selectively, blocking harmful IR radiation while maintaining visible transparency.

Inventive Principle:
Principle #32Color changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively protects against electric arcs by maintaining transparency and thermal stability, offering enhanced safety and design flexibility for face shields, reducing manufacturing complications, and enabling tailored coloration and tinting.

Implementation Method 1

IR-blocking inorganic nanoparticles

Methodology Applied
Scientific EffectInfrared blocking: Absorption (EM radiation)

Implementation Method 2

electric-arc resistant face shield

Methodology Applied
Scientific EffectElectric arc resistance: Electric Arc

Implementation Method 3

heated in a reducing gas or inert gas atmosphere to form crystalline tungsten bronze nanoparticles

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 4

dispersed in a liquid solvent medium by wet milling with small diameter grinding media

Methodology Applied
Scientific EffectMechanical dispersion: Abrasion

Data Source

PatentEP2775193A3Electric-arc resistant face shield or lens including ir-blocking inorganic nanoparticles
Publication Date: 2015.01.28 HONEYWELL INTERNATIONAL INC
  • EP2775193A3 patent drawing
  • EP2775193A3 patent drawing
  • EP2775193A3 patent drawing

AI summary

A transparent electric-arc resistant composition is produced by preparing crystalline tungsten bronze nanoparticles and homogenously dispersing the nanoparticles in a transparent plastic matrix. The crystalline tungsten bronze nanoparticles are prepared by homogeneously mixing an aqueous solution of soluble tungsten and cesium salts and then drying the solution. The dried solution is then heated in a reducing gas or inert gas atmosphere to form crystalline tungsten bronze nanoparticles. Thereafter, a dispersion agent is added and the nanoparticles are dispersed in a liquid solvent medium by wet milling to form a dispersion mixture. The dispersion mixture is then mixed with polymer pellets to form a polymer mixture, and the polymer mixture is then extruded to yield polymer pellets containing highly homogeneously dispersed inorganic nanoparticles. During or after dispersion, additional particles, dyes, heat stabilizers or UV absorbers, may be added. A lens or shield (10) is then molded from the polymer pellets.