Tungsten Carbide Bonding via Localized Carbon Enrichment

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Solution Overview

Problem

Existing bonded tungsten carbide-based super hard alloy assemblies for honeycomb body forming dies face challenges in achieving high bonding strength and mechanical properties, particularly under high pressure conditions, due to embrittlement and wear issues.

Innovation Solution

A bonded tungsten carbide-based super hard alloy assembly is produced with a high carbon concentration region in the stainless steel member, ranging from 0.70 to 3.00 mm from the bonding surface, and containing elements like Ti, Nb, Mo, Ta, V, and Zr, which suppresses carbon penetration from the tungsten carbide-based super hard alloy, enhancing bonding strength and mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If carbon concentration is increased in the stainless steel member to suppress carbon penetration and improve bonding strength, then the mechanical properties deteriorate due to embrittlement

Engineering Contradiction:
Improvebonding strengthVSAvoidmechanical properties
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies local quality by creating a high carbon concentration region only at the bonding surface (0-0.5mm depth) of the stainless steel member, while maintaining lower carbon concentration (0.03-0.10 mass%) in the bulk material. This localized carbon enrichment suppresses carbon penetration from the tungsten carbide alloy at the interface without causing embrittlement throughout the entire component, thus resolving the contradiction between bonding strength and mechanical properties.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes parameter changes by controlling the carbon concentration gradient through carburization treatment parameters (temperature, time, atmosphere). By optimizing these parameters, the carbon concentration is increased specifically at the bonding surface region while maintaining appropriate carbon levels in the bulk material, achieving both high bonding strength and preserved mechanical properties.

Inventive Principle:
Principle #35Parameter changes

2Stress or pressure

If high pressure is applied during honeycomb body formation, then the bonding strength is tested, but the tungsten carbide-based super hard alloy becomes worn and embrittled

Engineering Contradiction:
Improvehigh pressureVSAvoidwear and embrittlement
Core Design Contradiction:
Stress or pressureVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary action by performing carburization treatment on the stainless steel member before bonding to pre-establish a high carbon concentration region at the bonding surface. This preliminary carbon enrichment creates a protective interface that prevents carbon depletion from the tungsten carbide alloy during subsequent high-pressure forming operations, thereby preventing embrittlement and wear under pressure.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent converts the potentially harmful carbon penetration that causes embrittlement into a beneficial high carbon concentration region at the bonding surface. By controlling and localizing this carbon enrichment, the harmful effect is transformed into a protective layer that actually prevents excessive carbon loss from the tungsten carbide alloy during high-pressure operations.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in a bonded assembly with improved bonding strength, mechanical strength, and resistance to embrittlement, enabling effective high-pressure applications without deterioration in mechanical properties.

Implementation Method 1

a high carbon concentration region in the stainless steel member, ranging from 0.70 to 3.00 mm from the bonding surface, and containing elements like Ti, Nb, Mo, Ta, V, and Zr, which suppresses carbon penetration from the tungsten carbide-based super hard alloy

Methodology Applied
Scientific EffectCarbon penetration suppression: Diffusion Barrier

Data Source

PatentEP2689881B1Bonded object of tungsten carbide-based superhard alloy and process for producing same
Publication Date: 2019.10.16 NGK INSULATORS LTD
  • EP2689881B1 patent drawingFigure 1~2
  • EP2689881B1 patent drawingFigure 3~4
  • EP2689881B1 patent drawingFigure 5~7A

AI summary

Provided in the present invention is a bonded tungsten carbide-based super hard alloy assembly equipped with a first metal member having a first bonding surface and comprised of a steel material containing a martensite structure and a second metal member having a second bonding surface directly bonded to the first bonding surface of the first metal member and comprised of a tungsten carbide-based super hard alloy. The martensite structure-containing steel material which constitutes the first metal member is a stainless steel having an average carbon concentration of from 0.10 to 0.40 mass%. The first metal member has a high carbon concentration region at a depth ranging from 0.70 to 3.00mm from the first bonding surface. The high carbon concentration region has a maximum carbon concentration of from 0.3 to 1.2 mass%. The bonded tungsten carbide-based super hard alloy assembly has both high bonding strength and excellent mechanical strength.