Tungsten Disulfide Silane Coating for Sliding Surface Crack Suppression

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing methods for forming a coating film on sliding members to prevent damage propagation are not sufficient in effectively suppressing crack formation and flaking, particularly under repeated load conditions.

Innovation Solution

A method involving a lubricant composition containing tungsten disulfide and a silane compound, such as dialkoxysilane or trialkoxysilane, is applied in two contact steps to form a coating film on the sliding surface, where the tungsten disulfide enters the crack to reduce oil film pressure and the silane compound acts as a binder to extend flaking life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a coating film is formed using only a silane compound as disclosed in PTL 1, then the method is simple, but the suppression effect of damage propagation is insufficient

Engineering Contradiction:
Improvesimplicity of methodVSAvoidsuppression effect of damage propagation
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent combines tungsten disulfide particles and silane compound to form a composite coating film. The tungsten disulfide particles (0.1-10 μm) provide mechanical filling and stress distribution, while the silane compound forms a chemical bond network, creating a synergistic composite structure that enhances crack propagation suppression compared to using silane alone.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The coating film exhibits local quality differentiation where tungsten disulfide particles are strategically distributed within the silane matrix. The particles concentrate at stress concentration points and crack peripheries, providing localized reinforcement and stress distribution exactly where needed to suppress crack propagation.

Inventive Principle:
Principle #3Local quality

2Device complexity

If the sliding surface is left without a coating film, then the structure remains simple, but cracks propagate easily causing flaking

Engineering Contradiction:
Improvestructural simplicityVSAvoidflaking life
Core Design Contradiction:
Device complexityVSDuration of action of stationary object

Solution Approach 1:

The coating film is applied in advance to the sliding surface before operational damage occurs. The tungsten disulfide particles and silane compound form a pre-positioned protective barrier that proactively suppresses crack initiation and propagation, extending the service life of the sliding surface before flaking would otherwise occur.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The coating film acts as a cushioning layer between the sliding surface and external stresses. The tungsten disulfide particles absorb and distribute impact stresses, while the silane matrix provides elastic compliance, collectively cushioning against loads that would otherwise cause crack propagation and flaking.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Duration of action of stationary object

If a coating film is formed to suppress crack propagation, then flaking life is extended, but the coating film must withstand repeated load conditions

Engineering Contradiction:
Improveflaking lifeVSAvoidrepeated load condition
Core Design Contradiction:
Duration of action of stationary objectVSStress or pressure

Solution Approach 1:

The coating film changes the stress parameters at the sliding surface by introducing a compliant intermediate layer. The silane compound provides elastic deformation capacity under repeated loads, while tungsten disulfide particles redistribute stress concentrations, effectively reducing the peak stresses that drive crack propagation during cyclic loading.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The coating film extracts or isolates the sliding surface from the full impact of repeated loads. By positioning the tungsten disulfide-silane composite layer between the external load and the base sliding surface, the film absorbs and dissipates load energy, protecting the underlying material from stress-induced crack propagation.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively suppresses crack propagation and extends the flaking life of sliding members by reducing stress amplitude in the crack peripheral region and ensuring the tungsten disulfide particles remain bonded within the crack.

Implementation Method 1

the tungsten disulfide enters the crack to reduce oil film pressure

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

the silane compound acts as a binder to extend flaking life

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS12195694B2Method for forming coating film and lubricating oil composition
Publication Date: 2025.01.14 MITSUBISHI HEAVY IND LTD
  • US12195694B2 patent drawing
  • US12195694B2 patent drawing
  • US12195694B2 patent drawing

AI summary

A method for forming a coating film on a sliding surface of a sliding member includes: a first contact step of supplying a lubricant composition containing tungsten disulfide to the sliding surface to bring the tungsten disulfide into contact with the sliding surface; and a second contact step of bringing a silane compound that is dialkoxysilane, trialkoxysilane, tetraalkoxysilane, or a polymer or a copolymer of dialkoxysilane, trialkoxysilane, and tetraalkoxysilane into contact with the sliding surface.