Tungsten Nitride Coverage Layer for Semiconductor Defect Reduction

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Solution Overview

Problem

The scaling down of semiconductor devices poses challenges in achieving improved performance, quality, and yield due to issues such as defect formation during the fabrication process, particularly with conductive features like tungsten, which are prone to defects when exposed to oxygen or air.

Innovation Solution

A semiconductor device design that includes a coverage layer of tungsten nitride on top of conductive features, such as bit line contacts and vias, formed using reducing agents like titanium tetrachloride or tantalum tetrachloride to prevent exposure to oxygen and reduce defect formation, combined with a fabrication method that positions these features strategically within the device structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conductive features are exposed to oxygen or air during fabrication, then the fabrication process is simplified, but defect formation increases

Engineering Contradiction:
Improvefabrication process simplicityVSAvoiddefect formation
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

A coverage layer comprising tungsten nitride is introduced as an intermediary between the conductive feature (tungsten) and the oxygen-containing environment. This coverage layer prevents direct contact between oxygen and the conductive feature, thereby reducing defect formation without complicating the fabrication process

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The coverage layer creates an inert environment around the conductive feature by preventing oxygen exposure. This effectively protects the conductive feature from oxidation and defect formation during fabrication and operation

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Productivity

If scaling down is pursued to improve computing ability, then device performance increases, but defect formation and quality issues worsen

Engineering Contradiction:
Improvecomputing abilityVSAvoidquality and yield
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical state of the conductive feature surface by forming a coverage layer of tungsten nitride. This parameter change (from pure tungsten to tungsten nitride surface) prevents oxidation and defect formation, enabling continued scaling while maintaining quality and yield

Inventive Principle:
Principle #35Parameter changes

3Area of stationary object

If conductive features are made smaller for scaling, then device density increases, but oxidation and defect formation increase

Engineering Contradiction:
Improvedevice densityVSAvoidoxidation and defect formation
Core Design Contradiction:
Area of stationary objectVSObject-affected harmful factors

Solution Approach 1:

A thin film coverage layer of tungsten nitride is applied over the conductive feature. This thin film provides effective protection against oxidation and defect formation while maintaining the small dimensions and high density of the scaled-down device

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of tungsten nitride coverage layers effectively reduces defect formation in semiconductor devices, thereby increasing yield and improving the reliability and quality of the devices by protecting the conductive features from oxidation.

Implementation Method 1

cleaning the conductive feature comprises applying a reducing agent to the top surface of the conductive feature, and the reducing agent is titanium tetrachloride, tantalum tetrachloride, or a combination thereof

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 2

forming a coverage layer comprising tungsten nitride positioned on a top surface of the conductive feature... to prevent exposure to oxygen and reduce defect formation

Methodology Applied
Scientific EffectOxidation prevention: Oxidation

Data Source

PatentUS10978549B2Semiconductor device and method for fabricating the same
Publication Date: 2021.04.13 NAN YA TECH
  • US10978549B2 patent drawing
  • US10978549B2 patent drawing
  • US10978549B2 patent drawing

AI summary

The present application discloses a semiconductor device and a method for fabricating the semiconductor device. The semiconductor device includes a substrate, a conductive feature comprising tungsten positioned above the substrate, a coverage layer comprising tungsten nitride positioned on a top surface of the conductive feature, and a plurality of capacitor structures positioned above the substrate.