Composite Tungsten Oxide Insulation Nanoparticles for IR Blocking

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Solution Overview

Problem

Current thermal insulation media have single inorganic or organic structures that lack the combined advantages of both, leading to suboptimal energy efficiency and stability, and there is a need for a composite thermal insulation medium with improved properties.

Innovation Solution

An organic-inorganic composite thermal insulation medium is developed, comprising nanoparticles with a structure of (Mx-Rn)WOy, where M represents a doped metal element, R represents an organic complex group, and the medium is prepared through a multi-step process involving dispersion, reaction, and crosslinking heat treatment to achieve a tightly-connected structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If single inorganic or organic structure thermal insulation media are used, then the preparation process is simple, but the thermal insulation performance and stability are suboptimal

Engineering Contradiction:
Improvethermal insulation performanceVSAvoidstructure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining inorganic tungsten oxide nanoparticles with organic dyes to create a hybrid thermal insulation medium. The inorganic component provides thermal insulation properties while the organic component enhances infrared absorption, achieving superior thermal insulation performance compared to single-structure materials.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent merges inorganic and organic materials into a unified nanoparticle structure. The inorganic tungsten oxide core is coated with organic dye molecules, creating a composite nanoparticle that integrates the advantages of both material types to achieve enhanced thermal insulation and infrared absorption characteristics.

Inventive Principle:
Principle #5Merging (Combining)

2Reliability

If composite structure thermal insulation media are developed, then thermal insulation performance is improved, but the preparation process becomes complex

Engineering Contradiction:
Improvethermal insulation performanceVSAvoidpreparation process simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent segments the preparation process into distinct sequential steps: (1) synthesizing inorganic tungsten oxide nanoparticles, (2) dispersing them in solvent, (3) adding organic dye, (4) ultrasonic treatment, and (5) aging. This segmentation makes the complex composite formation process more manageable and reproducible.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs preliminary actions by first synthesizing and characterizing the inorganic tungsten oxide nanoparticles before incorporating the organic dye component. This preliminary preparation ensures the inorganic framework is ready and stable before the final composite structure is formed, simplifying the overall process control.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If nanoscale structure is used, then thermal insulation performance and transparency are enhanced, but manufacturing precision requirements increase

Engineering Contradiction:
Improvethermal insulation performanceVSAvoidparticle size control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent controls nanoparticle size by adjusting key parameters including tungsten oxide precursor concentration, pH value (controlled by acetic acid addition), and aging time. By optimizing these parameters, the patent achieves consistent nanoscale particle sizes that provide both thermal insulation performance and transparency while managing manufacturing precision requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite medium exhibits strong infrared absorption, high thermal insulation performance, weather resistance, and transparency due to its nanoscale structure, enhancing energy efficiency and product stability.

Implementation Method 1

the thermal insulation media could absorb infrared light and ultraviolet light, convert them into heat or reflection

Methodology Applied
Scientific EffectInfrared absorption: Absorption (EM radiation)

Implementation Method 2

transfer heat to the air in the forms of heat conduction and heat convection

Methodology Applied
Scientific EffectHeat conduction: Conduction (thermal)

Implementation Method 3

transfer heat to the air in the forms of heat conduction and heat convection

Methodology Applied
Scientific EffectHeat convection: Convection

Implementation Method 4

the thermal insulation media could absorb or reflect infrared light back indoors

Methodology Applied
Scientific EffectInfrared absorption: Absorption (EM radiation)

Implementation Method 5

about half of the heat is returned to the indoor air in the form of heat convection

Methodology Applied
Scientific EffectHeat convection: Convection

Implementation Method 6

the composite thermal insulation medium is subjected to a crosslinking heat treatment to obtain organic-organic and organic-inorganic tightly-connected structures

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 7

the nanoscale of the thermal insulation medium could further enhance an absorption activity of the composite thermal insulation medium

Methodology Applied
Scientific EffectInfrared absorption: Absorption (EM radiation)

Data Source

PatentUS12600868B2Organic-inorganic composite thermal insulation medium and preparation method thereof
Publication Date: 2026.04.14 SHANGHAI HUZHENG IND CO LTD
  • US12600868B2 patent drawing

AI summary

Disclosed is an organic-inorganic composite thermal insulation medium, which is a nanoparticle having a structure of (Mx-Rn)WOy, where M represents a doped metal element, R represents an organic complex group, 0.3≤x≤0.7, 2<y<4, n represents a polymerization degree of the organic complex group, and n≥10; M is selected from the group consisting of an alkali metal, an alkaline earth metal, a transition metal, and a rare earth metal; and R is selected from the group consisting of pyrrole and a derivative thereof, aniline and a derivative thereof, and thiophene and a derivative thereof. In addition, also disclosed is a method for preparing the thermal insulation medium.