Tuning Photonic Resonators via Photo-Electrochemical Etching

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Solution Overview

Problem

Current methods for tuning micro- and nano-photonic resonators lack precision, scalability, and permanence, making it difficult to achieve multiple resonators with the same resonance wavelength, which is crucial for various applications including optical computers and sensors.

Innovation Solution

A method involving photo-electrochemical etching using a fluid containing ions, where light with a wavelength equal to the resonator's resonance is injected to trigger etching, allowing for precise tuning of resonators by adjusting the light wavelength to reach a targeted resonance, applicable to multiple resonators simultaneously.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional fabrication techniques (photolithography, plasma etching) are used to manufacture resonators, then manufacturing scalability is improved, but manufacturing precision deteriorates (precision no better than a few nanometers)

Engineering Contradiction:
Improvemanufacturing scalabilityVSAvoidresonance wavelength precision
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by performing photo-electrochemical etching on resonators after fabrication to adjust their resonance wavelengths. The resonators are first manufactured using conventional scalable techniques, then subsequently tuned by removing material through light-triggered etching in an ionic fluid environment. This two-step approach allows scalable manufacturing followed by precise individual or collective tuning.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes physical parameters by using light wavelength as a control parameter to trigger etching at specific resonance wavelengths. By varying the injected light wavelength, the etching process selectively removes material from resonators with matching resonance wavelengths, enabling precise control over the final resonance wavelength through material removal.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If nitrogen deposition is used to shift resonance wavelength, then tuning capability is improved, but operational complexity worsens (requires high-vacuum and cryogenic temperature)

Engineering Contradiction:
Improveresonance wavelength tuning capabilityVSAvoidoperational environment complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent replaces mechanical/physical systems (vacuum chambers, cryogenic cooling systems) with a chemical-optical system. Instead of using nitrogen deposition requiring high-vacuum and cryogenic equipment, the invention uses photo-electrochemical etching in ambient or controlled atmosphere with ionic fluids, triggered by optical fields. This substitution eliminates complex operational requirements while maintaining tuning capability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the operational parameters from extreme conditions (high-vacuum, cryogenic temperature) to ambient or mild controlled conditions. The etching process occurs in ionic fluids at temperatures and pressures compatible with standard laboratory or industrial environments, fundamentally changing the operational regime from extreme to benign conditions.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If photochromic thin films are deposited on resonators, then reversible tuning is improved, but device reliability deteriorates (layer degrades optical and mechanical properties)

Engineering Contradiction:
Improvereversible tuning capabilityVSAvoidoptical and mechanical property integrity
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent extracts the problematic photochromic layer from the system and replaces it with a photo-electrochemical process using ionic fluids. Instead of depositing a film that degrades the resonator, the invention uses a fluid-based etching process that removes material from the resonator surface without adding degrading layers. The tuning is achieved through controlled material removal rather than film deposition.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses a disposable ionic fluid environment for tuning rather than permanent film coatings. The ionic fluid can be removed or replaced after use, and the tuning process is permanent through material removal. This approach trades the reversible but degrading film approach for a permanent but non-degrading material removal approach.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Adaptability or versatility

If metallic electrodes are used for electric tuning, then tuning capability is improved, but optical quality deteriorates (metallic electrodes degrade optical properties)

Engineering Contradiction:
Improveresonance frequency tuning capabilityVSAvoidoptical property quality
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent replaces the electrical tuning mechanism with optical-field-based photo-electrochemical etching. Instead of using metallic electrodes and electrical fields to tune resonators, the invention uses injected optical fields to trigger chemical etching processes. This substitution eliminates metallic components that degrade optical properties while achieving frequency tuning through controlled material removal.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

5Productivity

If UV light photoelectrical etching is applied to the whole sample, then manufacturing scalability is improved, but measurement precision worsens (lacks spectral precision and site-specificity)

Engineering Contradiction:
Improvebatch tuning capabilityVSAvoidspectral precision
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent applies local quality by making the etching process site-specific through resonance wavelength selectivity. When light at a specific resonance wavelength is injected, only resonators matching that wavelength experience significant field enhancement and undergo etching. This allows selective tuning of individual resonators or subsets with matching wavelengths within a batch, combining scalability with spectral precision.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent inverts the conventional approach by using the resonator's own resonance property to select which resonators are etched, rather than using external masking or positioning methods. The resonance wavelength acts as a natural selector, and by controlling the injected light wavelength, the user determines which resonators undergo modification. This inversion of the selection mechanism enables both batch processing and spectral precision.

Inventive Principle:
Principle #13The other way round (Inversion)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves picometer precision and permanence, enabling scalable and fast tuning of multiple resonators to a common wavelength without degrading the devices, overcoming the limitations of existing techniques.

Implementation Method 1

a method involves a step of injecting light, having a light wavelength equal to a resonance wavelength, into the resonator so that the injected light resonates within the resonator and triggers a photo-electrochemical etching process enabled by the surrounding fluid containing ions

Methodology Applied
Scientific EffectPhoto-electrochemical etching: Photoelectric Effect

Implementation Method 2

the injected light resonates within the resonator and triggers a photo-electrochemical etching process enabled by the surrounding fluid containing ions, said etching process being enhanced by the optical resonance which amplifies light intensity in the photonic resonator

Methodology Applied
Scientific EffectOptical resonance: Resonance

Data Source

PatentEP3268783B1Method for tuning one or more resonators
Publication Date: 2019.05.08 UNIV PARIS DIDEROT PARIS 7
  • EP3268783B1 patent drawingFigure 1~2
  • EP3268783B1 patent drawingFigure 3~4
  • EP3268783B1 patent drawingFigure 5~6

AI summary

The invention concerns a method for tuning at a targeted resonance wavelength at least one micro and/or nanophotonic resonator, the resonator having dimensions defining resonance wavelength of said resonator, the resonator being immersed in a fluid containing ions so that the resonator is surrounded by said fluid, wherein the method comprises a step of injecting light, having a light wavelength equal to the resonance wavelength, into the resonator, so that the injected light resonates within the resonator and triggers a photo-electrochemical etching process enabled by the surrounding fluid containing ions, said etching process being enhanced by the optical resonance which amplifies light intensity in the photonic resonator, the etching decreasing dimensions of the photonic resonator, hereby lowering and tuning the resonance wavelength of the photonic resonator.