Tunnel Junction μLED Hydrogen Diffusion for Low Resistance

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Solution Overview

Problem

GaN-based micro light-emitting diodes (μLEDs) face challenges due to poor conductive anode conductivity resulting from high resistance of the p-doped GaN layer, leading to degradation of wall-plug efficiency and current crowding, which is exacerbated by the low miscibility of Mg atoms and the formation of magnesium-hydrogen complexes, making it difficult to form good ohmic contacts.

Innovation Solution

The implementation of a tunnel junction in μLEDs, which is annealed after mesa etching, allows for hydrogen diffusion out of the p-doped semiconductor layer through exposed side walls, reducing resistivity and eliminating the need for a regrowth step, thereby improving current spreading and contact formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If Mg-doped p-GaN layer is used to create the anode, then the p-n junction can be formed, but the high resistance of the p-doped layer degrades wall-plug efficiency and causes current crowding

Engineering Contradiction:
Improvewall-plug efficiencyVSAvoidhigh resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The anode structure is segmented into multiple layers: a highly doped p++-GaN contact layer with thickness of 50-200 nm for low resistance contact, and a lightly doped p-GaN layer for carrier injection. This segmentation allows each layer to optimize its function - the contact layer minimizes resistance while the active layer maintains proper doping for light emission

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different doping concentrations are applied to different regions of the p-GaN layer. The contact region uses heavy p++ doping (10^19-10^20 cm^-3) to reduce resistance, while the light-emitting region uses lighter p doping (10^18-10^19 cm^-3) to maintain proper carrier injection and avoid excessive free carrier absorption

Inventive Principle:
Principle #3Local quality

2Object-affected harmful factors

If Mg doping concentration is increased to reduce resistivity, then conductivity improves, but low miscibility of Mg atoms and Mg-H complex formation increase resistivity

Engineering Contradiction:
ImproveresistivityVSAvoiddoping process complexity
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

A thin highly doped p++-GaN contact layer is deposited first before the main p-GaN layer. This preliminary highly doped layer provides immediate low-resistance contact path, allowing the subsequent lightly doped layer to be optimized for light emission without worrying about resistance issues

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The tunnel junction acts as an intermediary structure between the p-GaN anode and the external circuit. It provides a low-resistance current path that bypasses the high-resistance p-GaN layer, effectively decoupling the electrical contact requirement from the light-emitting layer properties

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If regrowth process is used to activate p-GaN, then conductivity improves, but processing complexity and cost increase

Engineering Contradiction:
ImproveresistivityVSAvoidprocessing steps
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The highly doped p++-GaN contact layer is deposited with such high doping concentration that it self-activates upon deposition, providing immediate low-resistance contact without requiring subsequent regrowth or annealing steps. This preliminary action eliminates the need for complex post-processing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The activation step is extracted and eliminated from the process by using a deposition method that directly creates a highly conductive layer. The high doping concentration achieved during deposition bypasses the need for thermal activation that would otherwise be required to activate Mg dopants

Inventive Principle:
Principle #2Taking out (Extraction)

4Reliability

If tunnel junction is implemented, then current spreading improves and forward voltage reduces, but additional processing steps are required

Engineering Contradiction:
Improvecurrent spreadingVSAvoidprocessing steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The tunnel junction structure is merged with the existing p-GaN contact layer structure. The highly doped p++-GaN layer serves dual functions as both the contact layer and the tunnel junction, eliminating the need for separate tunnel junction processing steps

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The highly doped p++-GaN contact layer is designed to perform multiple functions: providing low-resistance ohmic contact, enabling tunnel junction current spreading, and serving as the anode contact. This multi-functionality reduces the number of separate components and processing steps required

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances wall-plug efficiency, reduces forward voltage, increases light extraction efficiency, simplifies processing, and improves the reliability of ohmic contacts by facilitating easier contact formation on the n-GaN layer, all while eliminating the need for costly regrowth processes.

Implementation Method 1

allows for hydrogen diffusion out of the p-doped semiconductor layer through exposed side walls

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

which is annealed after mesa etching

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS10573781B1Light emitting diode with tunnel junction
Publication Date: 2020.02.25 META PLATFORMS TECHNOLOGIES LLC
  • US10573781B1 patent drawing
  • US10573781B1 patent drawing
  • US10573781B1 patent drawing

AI summary

A light emitting diode (LED) is manufactured using a process in which hydrogen diffuses out of a p-doped semiconductor layer via an exposed side wall of the p-doped semiconductor layer. The process includes forming a light generation layer on a base semiconductor layer and forming the p-doped semiconductor layer on the light generation layer. A tunnel junction layer is formed on the p-doped semiconductor layer and a contact layer is formed on the junction layer. The process also includes etching through at least the contact layer, the tunnel junction layer, and the p-doped semiconductor layer to expose the side wall of the p-doped semiconductor layer and enabling hydrogen to diffuse out of the p-doped semiconductor layer at least partially through the exposed side wall.