Turboexpander Inlet Temperature Control in Cryogenic Air Separation

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Solution Overview

Problem

Existing cryogenic rectification plants face challenges in efficiently controlling liquid production rates and turboexpander efficiency due to variations in energy supply costs and operational conditions, leading to issues such as poor separation performance and potential damage to turbines.

Innovation Solution

A method and apparatus that manipulate the turboexpander inlet temperature and expansion ratio by dividing a compressed gaseous mixture into two streams, controlling their flow rates to maintain the exhaust temperature at saturation, allowing for greater variability in liquid production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the pressure of the compressed mixture is increased to vary the expansion ratio of the turboexpander, then liquid production rate is improved, but the mixture may be liquefied at the exhaust of the turbine causing poor efficiency and potential damage

Engineering Contradiction:
Improveliquid production rateVSAvoidturboexpander efficiency and safety
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the temperature parameter of the compressed stream by removing portions at different temperatures from the main heat exchanger. By controlling the flow rates of these temperature-different streams and combining them, the inlet temperature to the turboexpander is adjusted, which allows variation of liquid production rate while maintaining safe expansion conditions without liquefaction at exhaust.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The compressed stream is divided into two separate streams with different temperatures by removing them at different locations from the main heat exchanger. This segmentation allows independent control of temperature parameters, enabling precise adjustment of the combined stream temperature before turboexpander entry, thus resolving the contradiction between liquid production and turboexpander safety.

Inventive Principle:
Principle #1Segmentation

2Reliability

If the pressure is decreased to avoid liquefaction in turboexpander exhaust, then turboexpander safety is improved, but the temperature of the expanded stream increases causing liquids within the column to vaporize and loss of separation performance

Engineering Contradiction:
Improveturboexpander safetyVSAvoidseparation performance
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

By adjusting the temperature parameter of the compressed stream inlet to the turboexpander through controlled removal of streams at different temperatures from the main heat exchanger, the patent achieves optimal expansion conditions. This allows maintaining lower pressures that prevent exhaust liquefaction while controlling the expanded stream temperature to avoid excessive vaporization and maintain separation performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system uses feedback control by monitoring the temperatures and flow rates of the removed streams, adjusting their proportions in the combined stream to maintain optimal turboexpander inlet temperature. This feedback mechanism ensures that expansion conditions remain within safe and efficient parameters, preventing both exhaust liquefaction and excessive column vaporization.

Inventive Principle:
Principle #23Feedback

3Productivity

If flow to the turboexpander is adjusted by recycling air from the bottom of the higher pressure column to a compressor, then liquid product make is adjusted, but wide swings in air compression requirements occur

Engineering Contradiction:
Improveliquid product makeVSAvoidair compression requirements
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent extracts (removes) portions of the compressed stream at different temperatures directly from the main heat exchanger, bypassing the need for recycling air through the compressor. This extraction method allows adjustment of liquid product make by controlling the flow rates of removed streams, eliminating the wide swings in compression requirements that would result from recycling approaches.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the variability of liquid production, improves turboexpander efficiency, and prevents excessive vaporization in distillation columns, thereby optimizing plant operations and reducing energy costs.

Implementation Method 1

At least part of the combined stream is expanded with the performance of work within a turboexpander to supply refrigeration to the cryogenic plant

Methodology Applied
Scientific EffectAdiabatic expansion: Adiabatic Cooling

Implementation Method 2

cooling the compressed gaseous mixture by indirect heat exchange with mixture component streams after having been purified

Methodology Applied
Scientific EffectIndirect heat exchange: Heat Exchanger

Data Source

PatentUS8020408B2Separation method and apparatus
Publication Date: 2011.09.20 PRAXAIR TECH INC
  • US8020408B2 patent drawing
  • US8020408B2 patent drawing
  • US8020408B2 patent drawing

AI summary

Separation method and apparatus for separating a gaseous mixture, for example, air, in a cryogenic rectification plant in which a compressed stream is divided into subsidiary streams that are extracted from a main heat exchanger of the plant at higher and lower temperatures. The two streams are then combined and expanded in a turboexpander to generate refrigeration for the plant. The flow rates of the two streams are adjusted to control inlet temperature of a turboexpander supplying plant refrigeration and to minimize potential deviation of the turboexpander exhaust from a saturated vapor state. Control of the expansion ratio can advantageously be applied to allow variable liquid production from the rectification plant.