Two-Column Nitrogen Removal System for Ultra-Low Methane Emissions

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Solution Overview

Problem

Existing natural gas processing systems face challenges in achieving ultra-low greenhouse gas emissions in nitrogen vent streams while maintaining low nitrogen levels in sales gas streams, often requiring high capital and energy expenditures and struggling with carbon dioxide processing at higher concentrations.

Innovation Solution

A two-column fractionating system with efficient heat exchange and reflux mechanisms, including a high-pressure first column and a lower-pressure second column, allows for the production of multiple sales gas streams at different pressures, minimizing methane and nitrogen levels, and accommodating higher carbon dioxide concentrations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single fractionating column is used, then capital expenditures are reduced, but the nitrogen vent stream contains higher methane emissions (3-5% methane)

Engineering Contradiction:
Improvenumber of fractionating columnsVSAvoidmethane emissions in nitrogen vent stream
Core Design Contradiction:
Device complexityVSObject-generated harmful factors

Solution Approach 1:

The single fractionating column is divided into two separate columns operating at different pressures. The first column (high pressure) removes the bulk of nitrogen, while the second column (low pressure) achieves ultra-low methane emissions in the nitrogen vent stream. This segmentation allows each column to be optimized for its specific function, resolving the contradiction between simplicity and emission reduction.

Inventive Principle:
Principle #1Segmentation

2Object-generated harmful factors

If a two-column system is used, then methane emissions in nitrogen vent stream are reduced, but capital expenditures and energy requirements increase

Engineering Contradiction:
Improvemethane emissions in nitrogen vent streamVSAvoidnumber of fractionating columns
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The system uses dynamic pressure differentiation between the two columns, with the first column operating at high pressure (300-500 psig) and the second at low pressure (75-125 psig). This dynamic approach allows the system to achieve ultra-low methane emissions while optimizing energy consumption and capital expenditures by matching each column's operating conditions to its specific separation function.

Inventive Principle:
Principle #15Dynamics

3Ease of manufacture

If conventional single-column NRU systems are used, then equipment cost is reduced, but greenhouse gas emissions in nitrogen vent stream are higher

Engineering Contradiction:
Improveequipment costVSAvoidgreenhouse gas emissions
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The invention changes the operating pressure parameter between the two columns, with the first column operating at high pressure (300-500 psig) and the second at low pressure (75-125 psig). This parameter change enables the system to achieve ultra-low greenhouse gas emissions (less than 100 ppm methane) while managing equipment costs through efficient heat exchange and reflux mechanisms.

Inventive Principle:
Principle #35Parameter changes

4Stress or pressure

If the NRU column operates at higher pressure, then sales gas pressure is improved, but energy consumption for refrigeration and compression increases

Engineering Contradiction:
Improvesales gas pressureVSAvoidrefrigeration and compression energy
Core Design Contradiction:
Stress or pressureVSUse of energy by moving object

Solution Approach 1:

The system creates equipotentiality in pressure distribution by having the first column operate at high pressure (300-500 psig) to provide high-pressure sales gas directly, while the second column operates at low pressure (75-125 psig) for energy-efficient methane removal. This pressure stratification reduces the need for additional compression energy while maintaining high sales gas pressure.

Inventive Principle:
Principle #12Equipotentiality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves ultra-low methane emissions in nitrogen vent streams, reduces energy requirements, and enables processing of natural gas with up to 2500 ppm CO2, producing high-purity nitrogen for product use and multiple sales gas streams at optimized pressures.

Implementation Method 1

processing a feed stream containing natural gas through a first fractionating column operating at a first pressure to produce a first bottoms stream and a first overhead stream, the first overhead stream being fed into a second fractionating column operating at a second pressure

Methodology Applied
Scientific EffectFractional distillation: Distillation

Implementation Method 2

A first heat exchanger cools a portion of the feed stream through heat exchange with a first portion of the first column bottoms stream

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Data Source

PatentUS20250251189A1System and Method for Separating Nitrogen from Methane with Ultra-Low Greenhouse Gas Emissions
Publication Date: 2025.08.07 BCCK HOLDING CO
  • US20250251189A1 patent drawing
  • US20250251189A1 patent drawing

AI summary

A system and method for removing nitrogen from natural gas using two fractionating columns to achieve an ultra-low greenhouse gas content in a nitrogen vent/product stream, while also producing three sales gas streams at different pressures and with low nitrogen content within pipeline specifications. A portion of a low pressure column overhead stream may be compressed and cooled and recycled back to provide reflux to the low pressure column. A system feed stream is cooled upstream of feed a high pressure column, but preferably not separated into streams with varying compositions. A portion of the high pressure column bottoms stream and the low pressure column bottoms stream provides refrigerant to the high pressure column to produce a reflux stream. An amount of methane in a nitrogen vent/nitrogen product stream may be less than 0.01%.