Two-Component Adhesive Composition for Balanced Plastic Bonding

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Solution Overview

Problem

Conventional two-component acrylic adhesive agents struggle to achieve balanced adhesion to a wide range of plastic resins, including both low-surface energy and high-surface energy materials, often requiring complex surface treatments and failing to provide sufficient adhesive force.

Innovation Solution

A two-component adhesive composition comprising a radically polymerizable compound, a polymerization initiator, and a reducing agent, which are mixed immediately before application, allowing for balanced adhesion to various plastic resins through a curing process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional two-component acrylic adhesive agents are used, then adhesion to some plastic resins can be achieved, but balanced adhesion to a wide range of plastic resins from low-surface energy to high-surface energy cannot be attained

Engineering Contradiction:
Improveadhesion rangeVSAvoidadhesive force
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the adhesive agent by incorporating specific polymers with functional groups that react with both low-surface energy and high-surface energy plastic resins. This chemical parameter adjustment enables the adhesive to bond effectively across a broad spectrum of plastic materials without requiring multiple specialized adhesive formulations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite adhesive system comprising multiple polymer components with different functional characteristics. This composite formulation allows the adhesive to simultaneously interact with various plastic resin types through different bonding mechanisms, achieving balanced adhesion across diverse materials including polyethylene, polypropylene, polyacetal, nylon 6, PET, PBT, polydimethylsilicone, polyether ether ketone, modified polyphenylene ether, polyphenylene sulfide, cycloolefin polymer, cycloolefin copolymer, polymethylpentene, and liquid crystal polyester.

Inventive Principle:
Principle #40Composite materials

2Reliability

If surface treatment such as flame treatment, ITRO treatment, corona discharge, plasma treatment, oxidation with ozone or an oxidizing acid, or sputter etching is applied, then adhesion to difficult-to-bond base materials can be improved, but the treatment becomes complicated and expensive

Engineering Contradiction:
Improveadhesive forceVSAvoidsurface treatment complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts and eliminates the need for complex surface treatment procedures by incorporating surface-active components directly into the adhesive formulation. The adhesive contains functional groups that can chemically bond to plastic surfaces without requiring preliminary flame treatment, corona discharge, or other complex surface modification processes, thereby simplifying the overall bonding process while maintaining reliable adhesive force.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention introduces intermediary functional groups within the adhesive composition that act as mediators between the adhesive and plastic surfaces. These functional groups enable direct chemical bonding to both low-surface energy and high-surface energy plastics without requiring intermediate surface treatment steps, effectively bridging the gap between adhesive and substrate while eliminating complex treatment requirements.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If primers containing high-surface energy material are coated, then adhesion to difficult-to-bond base materials can be achieved, but sufficient attachment of primers requires surface treatment

Engineering Contradiction:
Improveadhesive forceVSAvoidsurface treatment requirement
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the functions of primer and adhesive into a single integrated formulation. The adhesive composition incorporates surface-active components that enable direct bonding to difficult-to-bond plastics without requiring a separate primer coating step. This unified approach eliminates the need for preliminary surface treatment to attach primers, while still achieving sufficient adhesive force through the combined bonding capabilities of the single-agent formulation.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves balanced adhesion to a variety of plastic resins, including polyethylene, polypropylene, and polycarbonate, without the need for complex surface treatments, providing high peel strength and impact resistance.

Implementation Method 1

a radically polymerizable compound; a polymerization initiator; and a reducing agent

Methodology Applied
Scientific EffectRadical polymerization: Photopolymerisation

Data Source

PatentEP4130179B1Two-component adhesive composition
Publication Date: 2025.09.24 NIPPON SODA CO LTD
  • EP4130179B1 patent drawing
  • EP4130179B1 patent drawing
  • EP4130179B1 patent drawing

AI summary

An object of the present invention is to provide a two-component adhesive composition that may attain balanced adhesion of a low-surface energy resin such as polyethylene (PE), polypropylene (PP), or polytetrafluoroethylene (PTFE) with one adhesive agent. The adhesive composition of the present invention comprises the following components (A) to (D): (A) a radically polymerizable compound; (B) (B-1) a polymer consisting of at least one repeat unit derived from a polymerizable compound of formula (I), or (B-2) a polymer consisting of at least one repeat unit derived from a polymerizable compound of formula (I), and at least one repeat unit derived from another radically polymerizable compound; (C) a polymerization initiator; and (D) a reducing agent.