Two-Component Coating Composition for Erosion Resistance

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Solution Overview

Problem

Current erosion-resistant coatings for applications like rotor blades and aircraft face challenges in achieving high erosion resistance, UV resistance, and sandability while being easy to produce and apply, especially on large components, and often require UV initiators or high temperatures.

Innovation Solution

A two-component coating composition comprising a base paint component with polycarbonate diol, polyaspartic acid ester, and organosilane-modified filler, and a hardener component with hexamethylene diisocyanate isocyanurate, which can be processed at room temperature without UV initiators or high temperatures, providing excellent erosion resistance and grindability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the thickness of coatings is increased to improve erosion resistance, then erosion resistance is improved, but weight increases

Engineering Contradiction:
Improveerosion resistanceVSAvoidweight
Core Design Contradiction:
ReliabilityVSWeight of moving object

Solution Approach 1:

The patent changes the chemical composition parameters of the coating by using aromatic polyester polyols with specific molecular weight ranges (2,000-10,000 g/mol) and controlling the NCO index (50-200), which allows achieving high erosion resistance with thinner coating layers, thus reducing weight while maintaining protective performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite coating system combining aromatic polyester polyols with isocyanate components (polylactone-modified isocyanate prepolymers or uretdione compounds) to achieve a synergistic effect where the aromatic structure provides erosion resistance while the composite formulation maintains appropriate flexibility and elasticity, enabling thin-film high-performance coatings

Inventive Principle:
Principle #40Composite materials

2Strength

If resins with aromatic resin components such as epoxy resins are used to increase wear resistance, then wear resistance is improved, but UV resistance deteriorates

Engineering Contradiction:
Improvewear resistanceVSAvoidUV resistance
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent specifies using aliphatic polyester polyols instead of aromatic epoxy resins, changing the chemical structure parameter to eliminate aromatic rings that absorb UV radiation, thereby achieving both wear resistance and UV resistance simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses polylactone-modified isocyanate prepolymers as a temporary protective measure during application, which can be later replaced or cured to form the final durable coating with UV resistance

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Strength

If UV resins are used to achieve high crosslinking densities and improved wear resistance, then wear resistance is improved, but the choice of pigments is limited and layer thickness is restricted

Engineering Contradiction:
Improvewear resistanceVSAvoidpigment selection and layer thickness
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent controls the NCO index parameter (50-200) to regulate crosslinking density, achieving wear resistance while maintaining pigment compatibility and allowing flexible layer thickness adjustment from thin protective coatings to thicker wear-resistant layers

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a two-component system where the isocyanate component can be adjusted in proportion to achieve different crosslinking densities, allowing dynamic optimization of pigment selection and layer thickness based on specific application requirements

Inventive Principle:
Principle #15Dynamics

4Ease of repair

If a coating is made harder to improve sandability, then sandability is improved, but flexibility or elasticity deteriorates

Engineering Contradiction:
ImprovesandabilityVSAvoidflexibility or elasticity
Core Design Contradiction:
Ease of repairVSStability of the object's composition

Solution Approach 1:

The patent optimizes the molecular weight of the polyester polyol (2,000-10,000 g/mol) and the NCO index (50-200) to achieve a balanced crosslinking density that provides sufficient hardness for sandability while maintaining the flexibility needed for erosion resistance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite system combining rigid aromatic polyester structures for sandability with flexible aliphatic chains and controlled crosslinking to maintain elasticity, achieving both hard surface for sanding and flexible substrate for erosion protection

Inventive Principle:
Principle #40Composite materials

5Strength

If temperature-induced paints are used to achieve high crosslinking densities, then wear resistance is improved, but baking temperature limitations exist for large components

Engineering Contradiction:
Improvewear resistanceVSAvoidbaking temperature
Core Design Contradiction:
StrengthVSTemperature

Solution Approach 1:

The patent formulates the coating with isocyanate components that can achieve high crosslinking densities at reduced temperatures by optimizing the NCO index (50-200) and using polylactone-modified isocyanate prepolymers with appropriate reactivity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses polylactone-modified isocyanate prepolymers as intermediary compounds that mediate between the polyester polyol and the crosslinking agent, enabling gentler curing conditions suitable for large components while still achieving wear-resistant crosslinked networks

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating composition offers improved erosion resistance, UV resistance, and excellent sandability, making it suitable for high-stress applications like rotor blades and aircraft, with the ability to cure at low temperatures and maintain performance even before full hardening.

Implementation Method 1

a base paint component comprising (A) at least one polycarbonate diol, (B) at least one polyaspartic acid ester and (C) at least one filler modified with at least one organosilane and (2) a hardener component comprising (D) at least one hexamethylene diisocyanate isocyanurate containing aliphatic polyester groups

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentEP3105273B1Two component coating compositions and coatings produced therefrom having high erosion resistance
Publication Date: 2019.08.28 AKZO NOBEL COATINGS INT BV
  • EP3105273B1 patent drawing
  • EP3105273B1 patent drawing
  • EP3105273B1 patent drawing

AI summary

The invention relates to a two-component coating composition comprising (1) a base component comprising (A) at least one polycarbonate diol, (B) at least one polyaspartic ester, and (C) at least one organosilane-modified filler, and (2) a hardener component comprising (D) at least one hexamethylene diisocyanate isocyanurate which contains aliphatic polyester groups and has an isocyanate content of 5 to 23%. The invention also relates to a method for producing a coating using said coating composition as well as to the coatings produced according to said method.