Two-Stage Syngas Production with Separate Char and Gas Inputs

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Solution Overview

Problem

Existing methods for producing product gas from carbonaceous materials are inefficient and require high capital intensity, leading to increased costs and environmental impact.

Innovation Solution

A two-stage thermochemical process involving a first reactor for steam reforming and a second reactor for oxidizing char and converting hydrocarbons, with separate inputs for char and product gas, to produce a final product gas with reduced char and hydrocarbon content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single-stage gasifier is used to produce product gas from carbonaceous materials, then the process is simpler, but the capital intensity and physical outlay are high, and environmental impact is increased

Engineering Contradiction:
Improveprocess simplicityVSAvoidcapital intensity
Core Design Contradiction:
Device complexityVSEase of manufacture

Solution Approach 1:

The gasification process is divided into two separate stages: a first gasifier that produces crude syngas and char, and a second gasifier that further processes the char with hydrocarbon inputs. This segmentation allows each stage to be optimized independently, reducing overall capital intensity and physical outlay while maintaining process effectiveness.

Inventive Principle:
Principle #1Segmentation

2Productivity

If carbonaceous material is continuously introduced into the reactor at high throughput, then production efficiency increases, but maintaining reactor pressure and distributing feedstock uniformly becomes difficult

Engineering Contradiction:
Improvefeedstock throughputVSAvoidreactor pressure maintenance
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

By dividing the gasification process into two stages, the system can handle high feedstock throughput in the first gasifier while the second gasifier processes the char at a controlled rate. This segmentation allows each reactor to operate at optimized pressure and flow conditions, making it easier to maintain stable reactor pressure even at high overall productivity.

Inventive Principle:
Principle #1Segmentation

3Device complexity

If char is not separated from product gas, then the process is simpler, but the product gas quality is reduced due to higher char content

Engineering Contradiction:
Improveprocess simplicityVSAvoidproduct gas quality
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

Char is extracted and separated from the crude syngas stream between the first and second gasifiers. This extracted char is then fed into the second gasifier along with hydrocarbon inputs, allowing the final product gas to have reduced char content and improved quality while still utilizing all carbonaceous material for energy production.

Inventive Principle:
Principle #2Taking out (Extraction)

4Device complexity

If hydrocarbons are not converted in the second stage, then the process is simpler, but carbon intensity and energy efficiency are reduced

Engineering Contradiction:
Improveprocess simplicityVSAvoidcarbon intensity
Core Design Contradiction:
Device complexityVSUse of energy by moving object

Solution Approach 1:

The two-stage configuration enables the second gasifier to specifically target hydrocarbon conversion and char oxidation. This segmentation allows for enhanced carbon intensity and energy efficiency by ensuring complete utilization of both char and hydrocarbon components, while the modular design keeps the additional complexity manageable.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process reduces capital intensity, physical outlay, and environmental impact while increasing carbon intensity and providing a cost-effective installation for producing high-quality product gas.

Implementation Method 1

in a first reactor, steam reforming the carbonaceous material to produce a first product gas including char, hydrogen, carbon monoxide, carbon dioxide, and hydrocarbons

Methodology Applied
Scientific EffectSteam reforming: Chemical Transport Reactions

Implementation Method 2

in the second reactor, reacting the oxygen-containing gas with the separated char and the char-depleted product gas to produce a final product gas

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

hydrocarbons present within the char-depleted product gas are converted into additional product gas including hydrogen and carbon monoxide

Methodology Applied
Scientific EffectChemical conversion: Chemical Transport Reactions

Data Source

PatentUS12203040B2Two-stage syngas production with separate char and product gas inputs into the second stage
Publication Date: 2025.01.21 THERMOCHEM RECOVERY INTERNATIONAL INC
  • US12203040B2 patent drawing
  • US12203040B2 patent drawing
  • US12203040B2 patent drawing

AI summary

A two-stage syngas production method to produce a final product gas from a carbonaceous material includes producing a first product gas in a first reactor, separating char from the first product gas to produce separated char and char-depleted product gas, and separately reacting the separated char and the char-depleted product gas with an oxygen-containing gas in a second reactor to produce a final product gas. The separated char is introduced into the second reactor above the char-depleted product gas. The solids separation device may include serially connected cyclones, and the separated char may be entrained in a motive fluid in an eductor to produce a char and motive fluid mixture prior to being transferred to the second reactor. A biorefinery method produces a purified product from the final product gas.