Two-Step CMP Process for Residual Silicon Nitride Removal

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Solution Overview

Problem

The shallow trench isolation process in semiconductor fabrication faces challenges with residual silicon nitride formation during chemical mechanical polishing, particularly in diffusion areas, due to the wide variations in trench size, spacing, and density, leading to incomplete removal of dielectric layers and resulting in non-planar surfaces.

Innovation Solution

A two-step chemical mechanical polishing process using ceria-based compositions, where the first polishing step is followed by a rinse and a slurry purge, and then a second polishing step with ceria, effectively removing residual silicon nitride from diffusion areas, ensuring a planar surface without the need for reworking the wafer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If standard silica slurries are used for polishing silicon dioxide, then the oxide layer can be removed, but residual silicon nitride forms in the diffusion area

Engineering Contradiction:
Improvesurface planarityVSAvoidresidual silicon nitride formation
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The polishing process is divided into two distinct steps: first polishing with silica slurry to remove oxide, then switching to ceria slurry to remove residual nitride. This segmentation allows each polishing step to target specific materials with optimized selectivity, preventing residual nitride formation while maintaining surface planarity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the polishing slurry composition from silica-based to ceria-based for the second polishing step. This parameter change in slurry chemistry alters the polishing selectivity, enabling effective removal of residual silicon nitride that remained after the first silica-based polishing step.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If continued polishing is performed to remove residual oxide, then more oxide is removed, but residual silicon nitride formation is not reduced

Engineering Contradiction:
Improveoxide removal completenessVSAvoidsilicon nitride residue
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

Instead of continuing with the same silica-based polishing parameters, the invention changes the slurry composition parameter to ceria-based slurry. This chemical parameter change fundamentally alters the polishing mechanism and selectivity, enabling removal of residual nitride without requiring excessive oxide removal that would not solve the nitride residue problem.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If a single polishing step is used, then the process is simple, but residual silicon nitride remains in the diffusion area

Engineering Contradiction:
Improvepolishing process stepsVSAvoidresidual nitride removal
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The polishing process is segmented into two sequential steps with different slurry compositions: first step uses silica slurry for oxide removal, second step uses ceria slurry for nitride residue removal. This segmentation increases process steps but enables complete removal of residual nitride that cannot be achieved in a single polishing step.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces residual silicon nitride in diffusion areas, achieving a planar surface and improving the efficiency and throughput of the polishing process, eliminating the need for reworking the wafer and reducing operational costs.

Implementation Method 1

CMP combines both chemical action and mechanical forces and is commonly used to remove metal and dielectric overlayers

Methodology Applied
Scientific EffectChemical mechanical polishing:

Implementation Method 2

rinsing the first polished surface with a rinse composition to provide a rinsed surface

Methodology Applied
Scientific EffectRinsing:

Data Source

PatentUS7754611B2Chemical mechanical polishing process
Publication Date: 2010.07.13 MACRONIX INTERNATIONAL CO LTD
  • US7754611B2 patent drawing
  • US7754611B2 patent drawing
  • US7754611B2 patent drawing

AI summary

A chemical mechanical polishing method is disclosed. The method includes forming a film on a wafer having at least one trench structure thereon; polishing the surface of the film by providing a polishing composition to provide a first polished surface; rinsing the first polished surface with a rinse composition to provide a rinsed surface; and polishing the rinsed surface by providing a second polishing composition to provide a second polished surface.