Tyre Bead Elastomer Mixtures for Thermal Degradation Resistance

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Solution Overview

Problem

Heavy-duty tires face challenges in endurance under excessive loads and inflation pressures, leading to damage such as cracking in the bead area due to insufficient protection of the carcass reinforcement.

Innovation Solution

A tire design with a radial carcass reinforcement featuring a crown reinforcement and bead areas with specific elastomeric mixtures having a relative sulfur bridge density less than 5% in defined zones, combined with reinforcing elements oriented at angles less than 45°, provides enhanced protection and resistance to deformation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional elastomeric mixtures with high sulfur bridge density are used in the bead area, then the tire provides adequate protection against mechanical damage during assembly and disassembly, but the tire exhibits cracking and premature wear under excessive loads and inflation pressures due to insufficient resistance to temperature rises

Engineering Contradiction:
Improveendurance under excessive loadsVSAvoidsensitivity to temperature rises
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies different elastomeric compositions to different zones of the tire bead area. Specifically, the first and second elastomeric mixtures with low sulfur bridge density (less than 5%) are used in zones subject to high temperature rises (near the carcass reinforcement and stiffening elements), while traditional mixtures may be used in other areas. This local differentiation allows the tire to resist thermal degradation in critical zones without compromising overall structural integrity.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent fundamentally changes the chemical composition parameters of the elastomeric mixtures by reducing sulfur bridge density to less than 5% in specific zones. This parameter change transforms the material's thermal stability and resistance to temperature-induced cracking, enabling the tire to withstand excessive loads and inflation pressures that generate high temperatures in the bead area.

Inventive Principle:
Principle #35Parameter changes

2Strength

If the carcass reinforcement is anchored by turning around a rod in the bead area, then the tire structure gains strength and stability, but the elastomeric mixtures in this area are susceptible to cracking and damage under excessive use conditions

Engineering Contradiction:
Improvecarcass reinforcement protectionVSAvoidresistance to cracking under excessive use
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies elastomeric mixtures with specific low sulfur bridge density characteristics specifically in the zones adjacent to the carcass reinforcement and stiffening elements in the bead area. This localized application ensures that the most vulnerable regions (where cracking typically occurs under excessive use) are protected by material with superior resistance to thermal and mechanical degradation.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite elastomeric formulations combining specific polymers (such as polybutadiene, synthetic polyisoprene, or natural rubber) with controlled sulfur content and complementary additives. These composite materials provide both the structural compatibility needed for carcass reinforcement anchoring and the enhanced durability required to resist cracking under excessive loads and inflation pressures.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If traditional elastomeric mixtures are used throughout the tire, then the manufacturing process is simple and cost-effective, but the tire shows premature wear and reduced endurance in the bead area under heavy-duty conditions

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidtire life under heavy-duty conditions
Core Design Contradiction:
Ease of manufactureVSDuration of action of moving object

Solution Approach 1:

The patent implements a zoned approach where elastomeric mixtures with low sulfur bridge density are applied only in specific critical zones (defined by radial and axial dimensions around the bead area), while other areas may use conventional mixtures. This selective application maintains manufacturing simplicity through targeted material placement rather than complete redesign of the entire tire structure.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The tire exhibits improved endurance and resistance to aging, particularly during excessive use, with reduced sensitivity to temperature rises and improved rolling resistance, leading to extended tire life and performance.

Implementation Method 1

The tire exhibits improved endurance and resistance to aging, particularly during excessive use, with reduced sensitivity to temperature rises

Methodology Applied
Scientific EffectOxidation resistance: Oxidation

Implementation Method 2

reduced sensitivity to temperature rises and improved rolling resistance, leading to extended tire life and performance

Methodology Applied
Scientific EffectThermal stability: Thermal Expansion

Implementation Method 3

provides enhanced protection and resistance to deformation

Methodology Applied
Scientific EffectElastic deformation resistance: Elasticity

Implementation Method 4

the carcass reinforcement being anchored in each of the beads by turning around a rod

Methodology Applied
Scientific EffectMechanical anchoring: Mechanical Force

Data Source

PatentEP3319818B1Tyre comprising low-sulphur elastomer mixtures
Publication Date: 2019.09.04 MICHELIN & CO (CIE GEN DES ESTAB MICHELIN)
  • EP3319818B1 patent drawingFigure 1
  • EP3319818B1 patent drawingFigure 2
  • EP3319818B1 patent drawing

AI summary

The invention relates to a tyre having radial carcass reinforcement (2) consisting of a layer of reinforcing elements anchored in each of the beads by turning up around a bead wire (4), said turn-up of the carcass reinforcement being reinforced by at least one layer of reinforcing or stiffening elements (8). According to the invention, the relative density of sulphur bonds measured according to the method for inflation to equilibrium is lower than 5 % in at least 30 % of the elastomer mixtures contained in the surface of at least one area Z in a meridian plane, said elastomer mixtures being compositions based on at least one diene elastomer selected from the group of the diene elastomers consisting of the polybutadienes (in the abstract "BR"), the synthetic polyisoprenes (IR), natural rubber (NR), isoprene copolymers, butadiene copolymers except for the butadiene-nitrile copolymers (NBR), excluding the diene elastomers having carboxyl functions, and the mixtures of said diene elastomers.