Ultrafine Mineral Particle De-caking and Charge Neutralization

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Ultrafine particle fractions of materials like chalk, gypsum, and limestone face issues with caking during processing, storage, and transportation due to high cohesion forces and electrostatic charges, leading to difficulties in fluidization and separation, and increased risks of ignition and lumping.

Innovation Solution

Mechanical activation in an impact mill followed by separation using a dynamic separator and cyclone, combined with mechanical de-caking and electrostatic charge discharge in a disintegrator, and intense aeration to prevent caking and maintain free-flowing properties during storage and transport.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If mechanical activation and size reduction are applied to obtain ultrafine particles, then reactivity and surface area are improved, but cohesion forces and caking tendency increase

Engineering Contradiction:
Improveparticle size controlVSAvoidcaking tendency
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and removes electrostatic charges from particle surfaces using a corona discharge unit, separating this harmful property from the beneficial ultrafine particle characteristics. The corona discharge specifically targets and neutralizes electrostatic charges without affecting particle size or reactivity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the physical state of particles by controlling humidity levels during storage and transport. By maintaining specific humidity parameters, the cohesion forces between ultrafine particles are reduced, preventing caking while preserving the high reactivity and surface area properties.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If particles are ground to below 30-40 μm, then reactivity in hetero and homogenous reactions is improved, but natural angle of repose becomes negative due to high cohesion forces

Engineering Contradiction:
Improvereaction rateVSAvoidflowability
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent introduces controlled humidity as an intermediary factor that mediates between particle cohesion and flowability. By adjusting humidity levels, the patent creates optimal conditions where ultrafine particles maintain both high reactivity and adequate flow characteristics for handling and processing.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes environmental parameters (humidity and temperature) to control interparticle forces. By maintaining specific humidity ranges, the cohesion forces are modulated to allow ultrafine particles to flow properly while retaining their high surface area and reactivity properties.

Inventive Principle:
Principle #35Parameter changes

3Power

If electrostatic charges are present on particles, then mechanical activation is enhanced, but risk of electrostatic discharge and ignition increases

Engineering Contradiction:
Improvemechanical activation energyVSAvoidignition risk
Core Design Contradiction:
PowerVSObject-affected harmful factors

Solution Approach 1:

The patent selectively removes electrostatic charges from particle surfaces using corona discharge, separating the harmful electrostatic property from the beneficial mechanical activation effects. This neutralization process eliminates ignition risks while preserving particle reactivity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent converts the harmful electrostatic charges into a beneficial process by using corona discharge to neutralize them. The same electrical field that could cause ignition is harnessed to control and dissipate charges safely, transforming a hazard into a protective mechanism.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Quantity of substance

If polydispersed mixtures are transported and stored, then bipolar charges enhance inclination to congestions, but separation into particle fractions becomes more difficult

Engineering Contradiction:
Improveparticle concentrationVSAvoidseparation complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent applies preliminary electrostatic neutralization before transport and storage operations. By removing bipolar charges in advance using corona discharge, the patent prevents congestion issues during handling and simplifies subsequent separation processes, reducing overall system complexity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively produces ultrafine, non-caking, and electrostatically neutralized particles that can be stored and transported without lumping, ensuring consistent quality and safety by enhancing particle reactivity and porosity, thus preventing undesired caking and improving handling characteristics.

Implementation Method 1

mechanically activated, of high reactivity, deprived of electrostatic charges and protected against undesired caking

Methodology Applied
Scientific EffectImpact force: Impact Force

Implementation Method 2

sent through the pneumatic transport line

Methodology Applied
Scientific EffectAerodynamic force: Drag

Implementation Method 3

from the factions of particle sizes below 90 μm lifted by the stream of circulating gas to the upper part of dynamic separator

Methodology Applied
Scientific EffectCentrifugal force: Centrifugal Force

Implementation Method 4

mechanical de-caking and activation

Methodology Applied
Scientific EffectMechanical force: Mechanical Force

Implementation Method 5

intense aeration to prevent caking and maintain free-flowing properties

Methodology Applied
Scientific EffectAeration: Aeration

Implementation Method 6

deprived of electrostatic charges

Methodology Applied
Scientific EffectElectrostatic discharge: Electrostatic Discharge

Data Source

PatentEP2689854B1Method of obtaining protected against caking ultrafine fractions of rain raw materials such as chalk, gypsum, limestone, and system for this method execution
Publication Date: 2015.08.26 INNOWACYJNE PRZEDSIEBIORSTWO WIELOBRANZOWE POLIN
  • EP2689854B1 patent drawingFigure 1
  • EP2689854B1 patent drawingFigure 2

AI summary

Method of obtaining protected against caking, ultrafine particle fractions of raw materials such as chalk, gypsum and limestone in which the initial raw material is introduced to the impact mill (2), favourably a beater mill, where it is subject to crushing with simultaneous mechanical activation of particles, it is further delivered to the dynamic separator (4), it is subject to generation of fraction of particle sizes not exceeding 90 µm which is sent to the separating cyclone (5) where it is separated from the circulating gas and sent to the bunker (26), is according to the invention characterized by the fact that the obtained ultrafine loose material is, prior to further transport and storage, subject to customizing, i.e. mechanical de-caking and activation and discharge of electrostatic charges from the surface of particles in mechanical disintegrator (11) with simultaneous mixing, preliminary aeration in the chute cone of mechanical disintegrator (11), and then it is subject to intense process of aeration in pneumatic pressure pump (13) and transported to storage vessel (14). According to the invention version, additional loose material, favourably a halloysite is delivered to mechanical disintegrator (11) from additional vessel or set of vessels (21). The subject of the invention is also a system of this method execution. In systems of equipment according to the invention, by the method according to the invention, very fine particle fractions are obtained which are protected against undesired caking during their processing, storage, customizing, transportation and intended use.