Ultrasonic Viscosity Control for Spin Coating Planarity

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Solution Overview

Problem

Spin coating processes in semiconductor manufacturing face challenges in achieving planarity and reducing film shrinkage and cure time while minimizing topographical variations and volatile solvent content.

Innovation Solution

The use of ultrasonic viscosity control during spin coating by applying ultrasound waves to reduce the viscosity of the coating material, comprising a nonvolatile film material and a volatile solvent, to enhance film planarity and reduce topographical variations without increasing the molar percentage of the volatile solvent.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the molar percentage of volatile solvent in coating material is increased to reduce viscosity and improve planarity, then film planarity is improved, but film shrinkage and cure time increase

Engineering Contradiction:
Improvefilm planarityVSAvoidcure time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent applies ultrasonic waves to change the physical state of the coating material by temporarily reducing its viscosity through acoustic energy input. This allows the coating to spread more uniformly during spin coating without permanently altering the solvent composition, thereby improving planarity without increasing shrinkage or cure time

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Ultrasonic vibration is applied to the coating material during spin coating to reduce viscosity and improve planarity. The mechanical vibration energy from ultrasonic waves temporarily disrupts the molecular structure of the coating material, allowing better flow and distribution without requiring additional volatile solvent

Inventive Principle:
Principle #18Mechanical vibration

2Manufacturing precision

If ultrasonic waves are applied to reduce viscosity of coating material, then topographical variations are reduced and planarity is improved, but device complexity increases

Engineering Contradiction:
Improvetopographical variationsVSAvoidapparatus complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The rotor chuck is designed to perform multiple functions: it holds the substrate, provides rotational motion for spin coating, and simultaneously serves as the transducer for generating ultrasonic waves. This integration reduces device complexity by combining what would otherwise be separate components into a single multi-functional element

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The ultrasonic generation capability is merged with the rotor chuck structure itself. The rotor chuck contains a piezoelectric element that converts electrical energy to mechanical vibration, eliminating the need for separate ultrasonic transducers and reducing overall system complexity

Inventive Principle:
Principle #5Merging (Combining)

3Area of stationary object

If high rotational speed is used to spread coating material, then coating coverage is improved, but topographical variations and loss of planarity increase

Engineering Contradiction:
Improvecoating coverageVSAvoidtopographical variations
Core Design Contradiction:
Area of stationary objectVSManufacturing precision

Solution Approach 1:

Ultrasonic vibration applied to the coating material reduces its viscosity and allows it to flow more uniformly during spin coating. This prevents the formation of topographical variations that would otherwise occur at high rotational speeds, enabling both good coverage and planarity to be achieved simultaneously

Inventive Principle:
Principle #18Mechanical vibration

Solution Approach 2:

The viscosity of the coating material is dynamically changed during the spin coating process through ultrasonic application. This temporary viscosity reduction allows the coating to adapt to high rotational speeds without developing defects, enabling better control over topographical variations while maintaining adequate coverage

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces topographical variations and shortens the cure time while maintaining film planarity, improving the precision and efficiency of the spin coating process for semiconductor manufacturing.

Implementation Method 1

applying ultrasound waves to the coating material to reduce a viscosity of the coating material during the spin coating

Methodology Applied
Scientific EffectUltrasonic viscosity control: Ultrasonic Vibration

Implementation Method 2

The substrate spun at a high rotational speed, and the coating material is spread over the entire surface of the substrate by centrifugal force

Methodology Applied
Scientific EffectCentrifugal force: Centrifugal Force

Data Source

PatentUS11387099B2Spin coating process and apparatus with ultrasonic viscosity control
Publication Date: 2022.07.12 SANDISK TECHNOLOGIES LLC
  • US11387099B2 patent drawing
  • US11387099B2 patent drawing
  • US11387099B2 patent drawing

AI summary

A spin coating method includes dispensing a coating material including a nonvolatile film material and a volatile solvent over a substrate, and spin coating the coating material over the substrate by spinning the substrate while applying ultrasound waves to the coating material to reduce a viscosity of the coating material during the spin coating.