Undercoat Layer Composition for Photoreceptor Stability

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Solution Overview

Problem

The long-term cyclic stability of electrostatographic imaging members with typical zinc oxide/hydroxyanthraqinone undercoat layers is marginal, necessitating an improvement in photoreceptor performance.

Innovation Solution

A photoreceptor structure incorporating a conductive substrate with an undercoat layer composed of a binder resin, metal oxide particles, and compounds such as hydroxyquinoline, aminoquinoline, or quinoline acid, which supports a photosensitive layer, charge generation layer, and charge transport layer, enhancing the stability and performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a typical zinc oxide/hydroxyanthraqinone undercoat layer is used, then the undercoat layer can be easily manufactured, but the long-term cyclic stability of the imaging member is marginal

Engineering Contradiction:
Improvelong-term cyclic stabilityVSAvoidease of manufacture
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters of the undercoat layer by replacing hydroxyanthraqinone with hydroxyquinoline, aminoquinoline, or quinoline acid compounds. This parameter change in the chemical structure improves the long-term cyclic stability while maintaining the ease of manufacture through conventional coating processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite undercoat layer material combining metal oxide particles (zinc oxide, titanium oxide, or silicon oxide) with binder resin and quinoline-based compounds. This composite structure achieves both improved reliability through enhanced charge transfer properties and maintains manufacturability through standard coating techniques.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the undercoat layer composition is changed to improve stability, then the cyclic stability improves, but the device complexity increases

Engineering Contradiction:
Improvecyclic stabilityVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the chemical composition parameters within the same functional class (quinoline-based compounds) rather than introducing entirely new material systems. This approach improves cyclic stability while minimizing device complexity by maintaining compatibility with existing manufacturing and operational processes.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If a conventional undercoat layer is used, then the manufacturing process is simple, but the charge transfer performance is insufficient

Engineering Contradiction:
Improvecharge transfer performanceVSAvoidmanufacturing process complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent optimizes the chemical composition parameters of the undercoat layer by incorporating specific quinoline-based compounds with proven charge transfer capabilities. This enhances productivity through improved charge transfer performance while maintaining relatively simple manufacturing processes using conventional coating methods.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops a composite undercoat layer combining metal oxide particles, binder resin, and quinoline-based compounds to achieve superior charge transfer performance. The composite structure improves productivity while the use of standard coating techniques keeps the manufacturing process complexity manageable.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed structure improves the cyclic stability and performance of the photoreceptor by utilizing a specific undercoat layer composition that enhances charge transfer and image formation processes, leading to improved reliability and efficiency in electrostatographic devices.

Implementation Method 1

The undercoat layer includes a binder resin, metal oxide particles, and a compound selected from the group consisting of: a hydroxyquinoline, an aminoquinoline and a quinoline acid

Methodology Applied
Scientific EffectCharge transfer: Conduction (electrical)

Data Source

PatentUS10401747B1Undercoat layer for imaging device
Publication Date: 2019.09.03 XEROX CORP
  • US10401747B1 patent drawing
  • US10401747B1 patent drawing
  • US10401747B1 patent drawing

AI summary

Described herein is a photoreceptor. The photoreceptor includes a conductive substrate and an undercoat layer disposed on the conductive substrate. The undercoat layer includes a binder resin, metal oxide particles, and a compound selected from the group consisting of: a hydroxyquinoline, an aminoquinoline and a quinoline acid. The photoreceptor include a photosensitive layer disposed on the undercoat layer.