Dissolvable Unit Dose Paste Stabilization at High Surfactant Loading

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Solution Overview

Problem

Existing water-soluble unit dose articles with paste loading compositions face stability issues during storage and dosing, particularly when surfactant levels are high, leading to aggregation, sedimentation, and phase separation, which compromises dosing consistency and active ingredient levels.

Innovation Solution

Incorporating a polyalkylene polymer into the non-aqueous paste within a dissolvable unit dose article, specifically a polyalkylene graft copolymer with a polyalkylene oxide component as a graft base and polyvinyl ester and polyvinylpyrrolidone side chains, enhances stability and improves leakage performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If high levels of surfactants (more than 30%, 40%, or 45%) are included in the paste loading composition, then the cleaning effectiveness is improved, but the paste stability deteriorates leading to aggregation, sedimentation, and phase separation

Engineering Contradiction:
Improvesurfactant levelVSAvoidpaste stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

A thickening agent is introduced as an intermediary substance to mediate between the surfactant and solid particles. The thickening agent increases the paste viscosity and provides a stabilizing matrix that prevents direct interaction between incompatible components, thereby preventing aggregation and phase separation while allowing high surfactant levels to be maintained

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The paste is formulated as a composite material system consisting of surfactants, solid particles, and a thickening agent working together. The thickening agent creates a composite structure that provides both the desired high surfactant concentration for cleaning effectiveness and the structural integrity needed for storage stability

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If thickening agents including silica and clays are used to improve paste stability, then the paste stability is improved, but the total active ingredient level is compromised

Engineering Contradiction:
Improvepaste stabilityVSAvoidtotal actives level
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The invention changes the physical parameters of the paste by adjusting viscosity through the thickening agent rather than adding large quantities of inert fillers. This parameter change allows the paste to stabilize at high active ingredient concentrations without requiring dilution with inactive materials like excess silica or clay

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If solid particles and non-aqueous liquid are added together in high concentrations, then the cleaning performance is improved, but the paste becomes unstable with aggregation and sedimentation

Engineering Contradiction:
Improvesolid particles and non-aqueous liquid concentrationVSAvoidpaste stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The thickening agent serves as a mediator between solid particles and non-aqueous liquid, creating a stabilized suspension system. It provides a viscous continuous phase that keeps solid particles dispersed and prevents them from aggregating or settling, allowing high concentrations of both components to coexist stably

Inventive Principle:
Principle #24Intermediary (Mediator)

Data Source

PatentUS20250376646A1Dissolvable unit dose article containing high active paste
Publication Date: 2025.12.11 PROCTER & GAMBLE CO
  • US20250376646A1 patent drawing
  • US20250376646A1 patent drawing
  • US20250376646A1 patent drawing

AI summary

This present invention provides a dissolvable unit dose article containing high active paste.