Universal Primer Coatings for Inkjet and Electrophotographic Printing

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Solution Overview

Problem

Current primer coatings for liquid electrophotographic and inkjet printing are incompatible, requiring separate product lines and substrates due to their distinct properties, leading to increased costs and inventory management issues, as well as poor adhesion and water resistance.

Innovation Solution

Development of a primer composition featuring a polyvalent metal salt and an amine-functionalized copolymer with a specific amine number range, which forms a stable emulsion suitable for both printing techniques, ensuring compatibility and universal substrate suitability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If primer coatings with excessive functional groups (carboxylates, amines, alcohols) are used to promote strong chemical interactions and hydrogen bonding with toner, then toner adhesion is improved, but water resistance deteriorates

Engineering Contradiction:
Improvetoner adhesionVSAvoidwater resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the primer coating by incorporating specific polymers with controlled functional group densities. The primer includes polymers with carboxyl groups, amine groups, and hydroxyl groups in optimized proportions to achieve both strong toner adhesion through chemical interactions and adequate water resistance by avoiding excessive hydrophilicity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite primer coating system comprising multiple polymer components with complementary properties. The primer includes a mixture of polymers containing different functional groups (carboxylates, amines, alcohols) in specific ratios, creating a composite material that balances adhesion promotion with water resistance, preventing the drawbacks of using any single polymer type in excess.

Inventive Principle:
Principle #40Composite materials

2Strength

If primer coatings with excessive amine functional groups are used to promote toner adhesion, then chemical interactions are improved, but coating stability deteriorates due to corrosiveness and discoloration

Engineering Contradiction:
Improvetoner adhesionVSAvoidcoating stability
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent严格控制 amine group content in the primer coating, specifying that the primer includes polymers with amine groups but in limited quantities. The amine number is controlled within specific ranges to provide sufficient toner adhesion while preventing excessive corrosiveness and yellowing/discoloration over time, thus maintaining coating stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent distributes functional groups non-uniformly across different polymer components in the primer. Rather than using one polymer with high amine content, the primer uses multiple polymer types where amine groups are localized in specific components at controlled levels, while other components provide structural stability and resistance to degradation.

Inventive Principle:
Principle #3Local quality

3Manufacturing precision

If separate primer coatings are used for liquid electrophotographic and inkjet printing, then printing quality is improved, but product complexity and inventory management difficulty increase

Engineering Contradiction:
Improveprinting qualityVSAvoidproduct line complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent develops a universal primer coating composition that performs effectively for both liquid electrophotographic printing and inkjet printing. The primer includes polymers with multiple functional groups (carboxylates, amines, alcohols) in balanced proportions, creating a multi-functional coating that provides adequate adhesion and performance for different printing technologies, eliminating the need for separate primer products.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the requirements of two separate primer systems into a single composite primer formulation. By combining polymers with complementary functional groups in specific ratios, the primer simultaneously satisfies the adhesion requirements of electrophotographic toner and inkjet ink, consolidating what were previously two separate product lines into one universal product.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The primer composition provides excellent adhesion for both inkjet and liquid electrophotographic printing, reducing the need for separate substrates and coatings, enhancing print quality, and maintaining stability and resistance over time.

Implementation Method 1

the functional groups present within a primer coating may be chosen to promote strong chemical interactions such as, for example, hydrogen bonding or salt bridge formation, with complementary functional groups within the toner

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 2

Facilitate strong chemical adhesion of the toner to the surface of the substrate

Methodology Applied
Scientific EffectChemical adhesion: Chemical Bonding

Implementation Method 3

a primer composition featuring a polyvalent metal salt and an amine-functionalized copolymer with a specific amine number range, which forms a stable emulsion suitable for both printing techniques

Methodology Applied
Scientific EffectEmulsion formation: Emulsion

Data Source

PatentUS12134701B2Primer coatings for inkjet and liquid electrophotographic printing
Publication Date: 2024.11.05 MICHELMAN INC

AI summary

Aqueous primer compositions suitable for electrophotographic printing and inkjet printing are frequently incompatible with one another, such that coated substrates for each printing technique need to be stockpiled separately. Aqueous primer compositions containing components to facilitate both electrophotographic printing and inkjet printing and that remain compatible with each other may comprise a polyvalent metal salt dispersed in an aqueous fluid, and an amine-functionalized copolymer dispersed as an emulsion in the aqueous fluid, in which the amine-functionalized copolymer has an amine number of about 10 to about 180 mg KOH/g copolymer and a glass transition temperature of about 0° C. to about 50° C. Suitable amine-functionalized copolymers may be formed by an emulsion polymerization reaction of one or more first ethylenically unsaturated monomers lacking an amine group and one or more second ethylenically unsaturated monomers bearing at least one amine group.